Heitler W. — Elementary Wave Mechanics With Applications to Quantum Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Heitler W. — Elementary Wave Mechanics With Applications to Quantum Chemistry

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Название: Elementary Wave Mechanics With Applications to Quantum Chemistry

Автор: Heitler W.

Аннотация:

As this little book was primarily designed for the use of chemists and other non-mathematical readers I have added a section on diatomic molecules and above all much extended the chapters on the chemical bond. These are in the same elementary style as the rest of the book. I hope that these additions (which seem compatible with the idea of a small pocket book) will afford a good illustration of the methods of wave mechanics as well as its usefulness for chemical problems. To make the general theory more complete a section on the time-dependent wave equation has also been added.

Язык:

Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Издание: Second edition

Год издания: 1956

Количество страниц: 193

Добавлена в каталог: 16.08.2009

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Предметный указатель

$\Delta$ -states      110
$\mathrm{CH}_4$ , $\mathrm{CH}_2$ , $\mathrm{C}_2\mathrm{H}_2$ , etc.      see “Hydrocarbons”
$\mathrm{C}_2$ molecule      148
$\mathrm{NH}_2$       173
$\mathrm{N}_2$       121 140 154
$\mathrm{O}_2$ molecule      121 148
$\Pi$ -states      110
$\Sigma$ -states      110
Activation energy      167 187
Additivity of binding energies      188
Angular momentum of molecule      109 113
Angular momentum, orbital      61
Angular momentum, spin      59
Angular momentum, total      62
Antisymmetrical wave function      75 81 83 118 126 157
Atomic interaction curves      108 143
Balmer formula      38
benzene      189
Binding energy      see “Dissociation energy”
Bohr radius      35 131
boundary conditions      22 34
C atom, $^{5}\mathrm{S}$ -state      104 142
C atom, excited states      105
C atom, valency      142 147
Charge density      89 98 125
Closed shell      99 137 142
Complex wave functions      18 29 44 50
Constants of the motion      27 51 54 109
Continuous spectrum      39
Coulomb field      24
Coulomb field, energy, interaction, integral      89 130 152 160 180
Coupling, spin-orbit      63 66
Coupling, two spins      66 92
Crossing of atomic interaction curves      143
d, D-states      42 57 67
Degeneracy      40 44 74 95 144
Degeneracy, accidental      147; see also “change degeneracy”
Deuterium      164
Diffraction      2
Directional properties of valencies      171
Directional properties of valencies, quantization      57 60
Discrete quantum states      1 21
dispersion      6
Dissociation energy of $\mathrm{H}_2$       133
Dissociation energy of hydrocarbons      188
Double bond ( $\mathrm{C}_2\mathrm{H}_4$ )      188
Doublets      66 110
Effective charge of the nucleus      98
Eigenfunctions      23
Eigenvalues      23
Eigenvalues of hydrogen      34 37 42
Electron configuration, distribution      73 77 100
Electron configuration, pairs (chemical bond)      133 140 149
Equilibrium distance, of $\mathrm{H}_2$ molecule      133
Exchange charge density      90 130
Exchange charge density, degeneracy      75 126
Exchange charge density, energy, integral      89 128 153 161 181 185
Excited states influence on valency      149 151
Excited states of C atom      105
Excited states of H atom      37
Excited states on directional properties      1 77
Exclusion principle      76 82 117
Fine structure      64
Forbidden states      78
Free electron      17 29 37 192
frequency      1 4 7
Frequency of spin exchange      135
Frequency of vibration in diatomic molecules      116
Frequency of vibration of $\mathrm{H}_2$       134
Ground states      34 104 141
Group velocity      5 30
Hamiltonian      26
Helium atom      72 88 93
Helium atom, interaction with hydrogen      137
Heterpolar bond      123
Homopolar bond      123
Hydrocarbons      184
Hydrocarbons dissociation energy      188
Hydrogen atom      32
hydrogen molecule      124
Hydrogen molecule, ortho, para      120
Interaction energy, of two H-atoms      133

Interaction in $\mathrm{H}_2\mathrm{O}$       175
Interaction in diatomic molecules      152 183
Interaction in polyatomic molecules      180 186
Interaction of several H-atoms      163
Interaction of two electrons      91
Interference      2
ionic bond      123
Ionization energy      34 106
Lewis's electron pairs      142
Light quanta      2
Linear combinations of wave functions      43 95 146
Lithium, electron states      78
Localized bonds      see “Non-localized bonds”
Magnetic dipole      55
magnetic moment      55 60
Measurement      15
Modulated wave      30
Molecule, electronic states      107 154
Molecule, rotation      1 2 119
Molecule, vibration      115
Momentum      4 12
Monochromatic waves      12 17
Neutron      120
Non-localized bonds      166 170 189
Normalization      43 90 96
Nuclei      120
Operator      26 47
Ortho-molecules      120
Orthogonality relation      93 96
Oscillator      116
Overlap integral      129 160
p, P-states      39 43 52 67 171
Para-molecules      120
Particle velocity      4 6 31
Pauli-principle      see “Exclusion principle”
Periodic system      99 141
Perturbation energy      88 159
phase velocity      4
Potential barrier      36
probability      9 16 35 70
Quantum numbers      38 61
Quantum of action      1
Race      111 146
Rare gases      100 137
repulsive interaction      109 132 185
Rotational levels (molecule)      114 120
s, S-states      39 52 67
Saturation      123 138
Schroedinger equation      see “Wave equation”
screening      98
Sharp and unsharp quantities      10 13 47 54 166
Singlets      66 82
Size of an ion      138
Spin      59
Spin of molecule      110
Spin valency      139 149
Spin wave function      80 96
Spin, magnetic moment      60
standing waves      17 48
Superposition of valency structures      170 189
Superposition of waves      29 49
Symmetrical wave functions      75 81 118 126
Three-body forces      161
Time-dependent wave equation      28 49
Transition state      166
Triple bond ( $\mathrm{C}_2\mathrm{H}_2$ )      188
Triplets      66 82 110 193
Uncertainty relation      13 36 117
Valency of an atom      141 149
Valency structure      157 169 180
Van der Waals' forces      123
Vector addition rule      63 67
Vibrational levels (molecule)      116
Water molecule      171
Wave amplitude      8
Wave equation      18 24 28
Wave function of hydrogen      33 38 40
Wave function of oscillator      116
Wave function of s, p, d states      40 42 52 119 171
Wave length      3 7 29
Wave packet      5 49
Zeeman effect      55 60
Zero-point energy (vibration)      117

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