The term ‘supramolecular’ signifies that which is beyond the molecule, and
supramolecular concepts have consequently had the greatest influence in
organic chemistry where the molecule is paramount. Supramolecular chemistry
has gained in importance as it represents a point of departure from classical
organic chemistry which, since the time of Wohler, has continuously
emphasized that all physical and chemical properties of substances are
derivable from and are delimited by their molecular structures.
Supramolecular ideas have much relevance to modem organic chemistry,
and it is difficult to conceive of the recent advances in bio-organic chemistry,
catalysis and transport phenomena, chemistry at interfaces and organic
materials chemistry relying solely on molecule-based thought.