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Название: Conjugated polymer and molecular interfaces: science and technology for photonic and optoelectronic applications
Автор: Salaneck W.
Аннотация:
Although it would be difficult to describe in detail the evolution of the
science of condensed organic molecular solids over the past century, recognizable periods of activity can be identified. An abbreviated outline of the
lineage might be as follows: Evolving from a diverse array of work from
many different backgrounds and disciplines, there was a surge in interest in
the 1970s in the metallic one-dimensional charge transfer salts, as represented by the molecular crystal TTF-TCNQ, and in parallel, in the intercalated graphites. Based initially on these two classes of materials, the terminology synthetic metals was coined. The discovery of electrically
conducting organic polymers in the late 1970s provided a new focus for the
field and resulted in a natural scientific reorganization. During the 1980s,
conducting polymers matured as a unique class of materials: stable electronic
materials that combined the electrical and optical properties of metals and
semiconductors with the processing advantage and mechanical properties of
polymers. Organic (small-molecule) light-emitting devices (OLEDs)
emerged in the 1980s and became a new focus for research and development
in the 1990s. Light-emitting devices based on luminescent, semiconducting
polymers (PLEDs) evolved in the 1990s along with the more general development of ‘‘plastic electronics,’’ including photodiodes, photovoltaic
cells, thin-film transistors, and lasers. Although we have only just entered
the first decade of the new century, it seems that a principal focus will be
on the use of advanced printing technologies to fabricate such plastic electronic devices