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Название: Electroanalysis with carbon paste electrodes
Авторы: Svancara I., Kalcher K., Walcarius A.
Аннотация:
During the early days of his research, Professor Ralph N. Adams (RNA) was interested in the electrooxidation of organic compounds, mainly aromatic amines. The two principal materials used as
electrodes for such electro-oxidations were platinum and carbon in various physical configurations
(e.g., Pt as wire or planar foil and carbon as rods or sheets). A major problem with such solid electrodes, however, was the contamination and fouling of the electrode surface due to the product(s) of
these electro-oxidations. He kept thinking that it would be nice to have an electrode like dropping
mercury electrode (DME), which had a renewed surface with each new drop. Of course, Hg is not
used in the anodic potential range since it itself readily undergoes oxidation.