|
|
 |
| Авторизация |
|
|
|
| Поиск по указателям |
|
|
|
|
|
|
|
 |
|
|
|
| Scott R.P.W. — Liquid Chromatography Column Theory |
|
|
|
| Предметный указатель |
Adjusted retention time, definition 11
Adjusted retention volume, definition 11
Adsorption, detector, equation for on column detection 87
Adsorption, detector, heat, equation for output 83
Adsorption, detector, theory of 77
Adsorption, isotherms 43
Alumina, coated stationary phase 2
Alumina, limitations as an LC stationary phase 2
Analysis time, approximate for packed column 117
Analysis time, minimum, optimized open tube columns 222
Analysis time, minimum, optimized open tube columns, equation for 223
Analysis time, minimum, optimized, packed columns 194
Analysis time, minimum, optimized, packed columns, equation for 195
Analysis time, minimum, optimized, preparative columns 242
Analysis time, minimum, optimized, preparative columns, equation for 242
Analysis time, particle diameter 121
Analytical specifications for optimum column 183
Asymmetry, peak 41
Available stationary phase, definition 30
Axis of a chromatogram 96
Base line, definition 10
Capacity peak 67
Capacity peak, and capacity factor 71
Capacity peak, and capacity factor, equation for 70
Capacity peak, calculated from, exclusion volume 151
Capacity peak, calculated from, permeating volume 150
Capacity peak, effect on dispersion 149
Capacity peak, effect on dispersion, equation for 25
Capacity peak, explicit equation for 32
Capacity peak, optimized column 20
Capacity peak, optimized column, equation for 203
Capacity ratio 25
Cell detector, design for low dispersion 166
Cell detector, dispersion effect 164
Cell volume, effective, heat of adsorption detector 79
Charge, finite, elution curve of 39
Chromatogram, axes of 96
Chromatogram, reduced 177
Chromatography, nomenclature 9
Chromatography, vacancy 55
Chromatography, vacancy, applications 59
Chromatography, vacancy, equation of elution curve 59
Column, capillary 6
Column, characteristics of 1
Column, dead volume 10 27
Column, design, open tubular columns 215
Column, design, optimized open tube columns 231
Column, design, optimized open tube columns, program for 232
Column, design, optimized packed columns 206
Column, design, optimized packed columns, program for 208
Column, design, optimized preparative columns 250
Column, design, optimized preparative columns, program for 252
Column, design, packed 185
Column, design, preparative 238
Column, design, preparative, optimum particle diameter 239
Column, diameter versus particle diameter 171
Column, dispersion, efficiency 45
Column, dispersion, efficiency, equation for 46 47
Column, dispersion, environment 8
Column, dispersion, extra 153
Column, dispersion, extra, packed 102
Column, dispersion, flow rate, definition 10
Column, dispersion, flow rate, optimum for open tube 224
Column, dispersion, flow rate, optimum for packed 199
Column, dispersion, flow rate, optimum for preparative 247
Column, dispersion, frits, contribution to dispersion 164
Column, dispersion, heat capacity 8
Column, dispersion, length, approximate for packed column 117
Column, dispersion, length, optimum for open tube column 221
Column, dispersion, length, optimum for open tube column, equation for 222
Column, dispersion, length, optimum for packed column 192
Column, dispersion, length, optimum for packed column, equation for 192
Column, dispersion, length, optimum for preparative column 241
Column, dispersion, length, optimum for preparative column, equation for 241
Column, dispersion, length, particle diameter for maximum efficiency 120
Column, dispersion, length, particle limits 8
Column, dispersion, material of construction 6
Column, dispersion, open limitations 6 233
Column, dispersion, open minimum HETP 217
Column, dispersion, open tubular, flow rate 224
Column, dispersion, open tubular, flow rate, equation for 225
Column, dispersion, open tubular, optimum, design 215
Column, dispersion, open tubular, radius 218
Column, dispersion, open tubular, radius, equation 219
Column, dispersion, open tubular, velocity 217
Column, dispersion, overload 259
Column, dispersion, packed 6
Column, dispersion, packed, longitudinal diffusion 103
Column, dispersion, packed, longitudinal diffusion, equation for 104
Column, dispersion, packed, multipath 102
Column, dispersion, packed, multipath, equation for 103
Column, dispersion, packed, optimum, specifications for, in column design 182
Column, dispersion, packed, resistance to mass transfer, mobile phase 106
Column, dispersion, packed, resistance to mass transfer, stationary phase 106
Column, dispersion, physical nature of 6
Column, dispersion, physical properties of Zorbax column 37
Column, dispersion, purpose of 3
Column, dispersion, quartz, availability 7
Column, dispersion, radial equilibrium 100
Column, dispersion, radius, dependance on extra column dispersion 167
Column, dispersion, radius, equation for 169 170
Column, dispersion, radius, optimum, open tubular 218
Column, dispersion, radius, optimum, open tubular, equation for 219
Column, dispersion, radius, optimum, packed 196
Column, dispersion, radius, optimum, packed, equation for 198
Column, dispersion, radius, optimum, preparative 244
Column, dispersion, radius, optimum, preparative, equation for 246
Column, dispersion, resolving power 60
Column, dispersion, resolving power, equation for 62
Column, dispersion, theories 12
Column, dispersion, thermostat 8
Column, dispersion, volume, total, expression for 28
Column, dispersion, wall thickness, limitations 8
Column, dispersion, wall thickness, preparative 248
Column, dispersion, weight, limits 8
Computer program for the design of open tube columns 232
Computer program for the design of open tube columns, report for a packed column design 233
Computer program for the design of packed columns 208
Computer program for the design of packed columns, report for a packed column design 210
Computer program for the design of preparative columns 252
Computer program for the design of preparative columns, report for a packed column design 256
Connecting tubes, dispersion, cause 154
Connecting tubes, dispersion, equation for 155
Connecting tubes, length versus variance 157
Connecting tubes, low dispersion 158
Connecting tubes, low dispersion, coiled tubes 159
Connecting tubes, low dispersion, coiled tubes, H/u curves 161
Connecting tubes, low dispersion, serpentine tubes 161
Connecting tubes, low dispersion, serpentine tubes, H/u curves 162 163
Connecting tubes, pressure drop across 156
Constraints, instrument, in column design 179
Criteria for column performance 176
d'Arcy's law 116
Dead, point, definition 10
Dead, time definition 10
Dead, volume, definition 10
Dead, volume, discussion of 27
Dead, volume, kinetic 31
Dead, volume, thermodynamic 32
Design, equations for open tube columns 231
Design, equations for open tube columns, program for 232
Design, equations for packed columns 206
Design, equations for packed columns, program for 208
Design, equations for preparative columns 250
Design, equations for preparative columns, program for 252
Design, open tubular columns 215
Design, packed columns 185
Design, preparative columns 237
Design, protocol for columns 175
Detector, cell, design for low dispersion 166
| Detector, cell, dispersion, effect on 164
Detector, heat of adsorption, equation for on column detection 87
Detector, heat of adsorption, equation of output 83
Detector, heat of adsorption, theory 77
Differential equation for the elution curve 18
Diffusion coefficients, list of 268
Diffusion coefficients, peptides 270
Diffusivity relation to, longitudinal diffusion 143
Diffusivity relation to, minimum HETP 145
Diffusivity relation to, resistance to mass transfer 147
Dipole, induced 5
Dipole, interactions 5
Dispersion, detector cell dispersion, effect on 164
Dispersion, effect of sample volume 153
Dispersion, extra column 6 95 153
Dispersion, packed column 102
Dispersion, radial 99
Dispersion, radial, equation for 100
Dispersive forces 5
Dispersive interactions 5
distribution 4
Distribution, coefficient 16
Distribution, factors controlling 4
Effective, cell volume, heat of adsorption detector 79
Effective, plates 63
Effective, plates, equation for 64
Effective, plates, relation to equilibrium plates 65
Efficiency, column 45
Efficiency, equation for 46 47
Efficiency, particle diameter for a packed column 119
Efficiency, radius for an open tube column 132
Elective variables in column design 181
Elution curve equation 19 21
Elution curve, derivation 16
Elution curve, finite charge 39
Elution curve, Gaussian form 50
Elution curve, Gaussian form, equation for 52
Elution curve, solution of differential form 19
Elution, gradient 213
Elution, profile, of low aspect ratio tube 165
Environment, column 8
Equation, d'Arcy's, fluid flow through a packed bed 116
Equation, design for optimized packed column 206
Equation, efficiency required to effect a given separation 62
Equation, elution curve 19 21
Equation, elution curve, derivation 16
Equation, elution curve, finite charge 39 40
Equation, elution curve, Gaussian form 50
Equation, elution curve, Gaussian form, equation of 52
Equation, Giddings, dispersion in a packed column 123
Equation, Golay, for dispersion on open tubes 128
Equation, heat of adsorption detector 83
Equation, heat of adsorption detector, with on column detection 87
Equation, Horvath and Lin, for dispersion in a packed column 128
Equation, Huber, for dispersion in a packed column 124
Equation, Knox, for dispersion in a packed column 126
Equation, mass sensitivity 172
Equation, Poiseuille's, fluid flow through a tube 132
Equation, Van Deemter 109
Equation, Van Deemter, detailed 110
Equilibrium, radial, column 100
Extra column dispersion 6 95 153
Extra column dispersion, effect on column radius 167
Factors that control retention and selectivity 4
Finite charge, elution curve of 39
Flow rate, definition 10
Flow rate, for optimized open tube column 224
Flow rate, for optimized open tube column, equation for 224
Flow rate, for optimized packed column 199
Flow rate, for optimized packed column, equation for 199
Flow rate, for optimized preparative column 247
Flow rate, for optimized preparative column, equation for 247
Frits, column, contribution to dispersion 164
Giddings, equation for dispersion in a packed column 123
Golay, equation for dispersion in open tubes 128
Gradient elution 212
Heat of adsorption detector, equation for on-column detection 87
Heat of adsorption detector, equation of output 84
Heat of adsorption detector, theory 77
Height, peak, definition 11
HETP, curve, for open tubes 129
HETP, curve, for packed columns 111
HETP, curve, van Deemter 138
HETP, definition of 97
HETP, equation, for a packed column 110
HETP, equation, for an open tube column 128
HETP, equation, for an open tube, uncoated 129
HETP, minimum, dependance on diffusivity 145
HETP, minimum, open tube column 131 217
HETP, minimum, packed column 115
Horvath and Lin, equation for dispersion in a packed column 128
Huber, equation for dispersion in a packed column 124
Induced dipoles 5
Inflexion points, equation for 49
Inflexion points, of elution curve 48
Injection point, definition 9
Instrument constraints, in column design 179
Interstitial volume, definition of, and expression for 29
Interstitial volume, effect of ion volume of marker 34
Interstitial volume, moving 29
Interstitial volume, static 29
Ion volume, effect on interstitial volume 34
Ionic interactions 4
Isotherms, adsorptions 43
Isotherms, effect on peak shape 44
Kinetic dead volume 31
Knox, equation for dispersion in a packed column 126
Length, column, approximate for packed 117
Length, optimum for preparative 241
Length, optimum for preparative, equation for 241
Length, optimum, for open tube 221
Length, optimum, for open tube, equation for 221
Length, optimum, for packed 192
Length, optimum, for packed, equation for 192
Length, versus particle diameter, maximum efficiency 120
Length, versus radius for maximum efficiency 132
Line, base 10
List of symbols 265
Longitudinal diffusion, and diffusivity 143
Longitudinal diffusion, packed column 103
Longitudinal diffusion, packed column, equation for 104
Low aspect ratio tube, dispersion coiled tubes 159
Low aspect ratio tube, dispersion connecting tubes 158
Low aspect ratio tube, dispersion serpentine tubes 161
Low aspect ratio tube, dispersion, detector cell design 166
Low aspect ratio tube, elution profile of 165
Mass overload 261
Mass sensitivity 172
Maximum, efficiency, length and particle diameter 120
Maximum, extra column dispersion, open tube column 226
Maximum, extra column dispersion, open tube column, equation for 228
Maximum, peak, definition 11
Maximum, sample volume 53
Maximum, sample volume, equation for 54
Maximum, sample volume, optimized open tube, column 226
Maximum, sample volume, optimized open tube, column, equation for 228
Maximum, sample volume, optimized packed, column 204
Maximum, sample volume, optimized packed, column, equation for 204
Minimum, analysis time, optimized column 194
Minimum, analysis time, optimized column, equation for 195
Minimum, HETP, open tube column 217 131
Minimum, HETP, packed column 115
Minimum, HETP, packed column, relation to diffusivity 146
Minimum, solvent consumption, for optimized packed column 201
Mobile phase 4
Mobile phase, volume of, expression for 29
Molecular interactions 4
Molecular interactions, size, effect on retention volume 36
Moving phase, definition 29
Multipath dispersion 102
|
|
|
| Реклама |
|
|
|
|
|
|
|
|
О проекте