Content: DNA in metal catalysis / E.W. Dijk, B.L. Feringa, and G. Roelfes — Artificial metalloproteins exploiting vacant space : preparation, structure, and functions / S. Abe, T. Ueno, and Y. Watanabe — Manganese-substituted [alpha]-carbonic anhydrase as an enantioselective peroxidase / Q. Jing, K. Okrasa, and R.J. Kazlauskas — Directed evolution of stereoselective hybrid catalysts / M.T. Reetz — Artificial metalloenzymes for enantioselective catalysis based on the biotin-avidin technology / J. Steinreiber and T.R. Ward