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Название: Generalized Boltzmann Equation for Lattice Gas Automata
Авторы: Bussemaker H.J., Ernst M.H., Dufty J.W.
In this paper a theory is formulated that predicts velocity and spatial correlations between occupation numbers that occur in lattice gas automata violating semi-detailed balance. Starting from a coupled BBGKY hierarchy for the n-particle distribution functions, cluster expansion techniques are used to derive approximate kinetic equations. In zeroth approximation the standard nonlinear Boltzmann equation is obtained; the next approximation yields the ring kinetic equation, similar to that for hard-sphere systems, describing the time evolution of pair correlations. The ring equation is solved to determine the (nonvanishing) pair correlation functions in equilibrium for two models that violate semidetailed balance. One is a model of interacting random walkers on a line, the other one is a two-dimensional fluid-type model on a triangular lattice. The numerical predictions agree very well with computer simulations.