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Название: Fluctuations-Inclusive Approach to Phase Transitions in Binary Mixtures
Авторы: Pini D., Parola A.
Аннотация:
The hierarchical reference theory of fluids (HRT) is applied to the study of the phase diagram of binary mixtures of simple fluids. This approach implements the renormalization group machinery into a liquid-state theory in order to systematically deal with the effect of long-range correlations which play a crucial
role in the onset of criticality and phase separation. The effect of fluctuations is embodied in a partial differential equation (PDE) for the free energy of the mixture. Recently, a robust numerical algorithm has been developed which enabled us to integrate this PDE on a substantial density mesh even at low temperature, when the coexistence region spreads over most of the density concentration plane.