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Название: The Elimination of Fast Variables in Complex Chemical Reactions. II. Mesoscopic Level (Reducible Case)
Автор: Janssen J.A.M.
Аннотация:
The master equation for chemical reactions that proceed through a number of steps (complex reactions) is considered. Examples are studied in which the reaction constant of one of the steps is much larger than the others, and a reduced master equation is derived by means of a projection operator formalism. This reduction amounts to an elimination of intermediates.