Kenneth S. Alexander, Marek Biskup, Lincoln Chayes — Colligative Properties of Solutions: I. Fixed Concentrations
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Название: Colligative Properties of Solutions: I. Fixed Concentrations
Авторы: Kenneth S. Alexander, Marek Biskup, Lincoln Chayes
Аннотация:
Using the formalism of rigorous statistical mechanics, we study the phenom-
ena of phase separation and freezing-point depression upon freezing of solu-
tions. Specifically, we devise an Ising-based model of a solvent–solute system
and show that, in the ensemble with a fixed amount of solute, a macroscopic
phase separation occurs in an interval of values of the chemical potential of the
solvent.
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