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Название: Exact Solution of a Deterministic Model for Isomerization Kinetics
Автор: Elskens Y.
Isomerization kinetics is studied on a one-dimensional ideal gas model with deterministic transitions. The concentrations of species are found to satisfy the phenomenological rate laws appropriate for diffusion-controlled kinetics, and the various correlations are determined. In the long-time regime, higher correlations present long tails reflecting a strongly non-Markovian evolution.