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Название: Criticality and Phase Transitions in Ionic Fluids
Автор: Stell G.
Аннотация:
Journal of Statistical Physics, VoL 78, Nos. 1/2, 1995. p. 197-238.
Recent experimental investigations of criticality and phase separation in ionic fluids have revealed behavior of great theoretical interest. In seeking to understand the experiments, some of which appear to exhibit argonlike criticality and some of which exhibit "classical" (mean-field) criticality, a convenient starting point is the restricted primitive model (RPM) of symmetrically charged hard spheres, all of equal diameter tr, each sphere bearing a positive or negative charge of magnitude q...