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Reid R.C., Prausnitz J.M., Poling B.E. — The Properties of Gases and Liquids
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Íàçâàíèå: The Properties of Gases and LiquidsÀâòîðû: Reid R.C., Prausnitz J.M., Poling B.E.Àííîòàöèÿ: Completely rewritten and reorganized to reflect the latest developments in estimating the properties of gases and liquids, this new edition of the highly regarded reference presents a comprehensive survey of the most reliable estimation methods in use today. It provides instantly usable information on estimating both physical and thermodynamic properties when experimental data are not available (for example, constants such as critical temperature, critical pressure, acentric factor, and others); thermodynamic properties of gases and liquids, both pure and mixtures, including enthalpies, entropies, fugacity coefficients, heat capacities, and critical points; vapor-liquid and liquid-liquid equilibria as needed in separation operations such as distillation, absorption, and extraction. An invaluable reference that provides property values for more than 600 pure chemicals, this is the only book in its field to include a critical analysis of existing methods as well as practical recommendations.
ßçûê: Ðóáðèêà: Ôèçèêà /Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö ed2k: ed2k stats Èçäàíèå: fourth editionÃîä èçäàíèÿ: 1987Êîëè÷åñòâî ñòðàíèö: 741Äîáàâëåíà â êàòàëîã: 23.03.2006Îïåðàöèè: Ïîëîæèòü íà ïîëêó |
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Ïðåäìåòíûé óêàçàòåëü
Acentric factor 23 24 34 Acentric factor, table 656—732 Activity coefficients from ASOG group contribution method 313—314 Activity coefficients from azeotropic data 307—309 Activity coefficients from mutual solubilities 309—311 Activity coefficients from UNIFAC group contribution method 314—332 Activity coefficients, at infinite dilution 290—307 Activity coefficients, correlations for 254—257 Activity coefficients, definition of 248 Activity coefficients, estimation of 283—332 Activity coefficients, one-parameter correlations for 255—259 Ambrose estimation method for critical properties 12—14 Amoco Redlich-Kwong equation of state 44 346 Andrade correlation for liquid viscosity 439 Antoine vapor pressure equation 208 209 Aqueous solutions of electrolytes, phase equilibria of 375—379 ASOG (analytical solution of groups) group contribution method for activity coefficients 313—314 Athermal solution 262 Barker’s method for phase equilibrium calculations 272 Barner and Quinlan values 78 79 Barner and Quinlan values for Lee — Kesler equation 85—87 343 Barner and Quinlan values for Peng — Robinson equation 83 343 Barner and Quinlan values for Soave equation 83 343 Baroncini et al. estimation method for thermal conductivity of liquid mixtures 562 563 Benedict — Webb — Rubin (BWR) equation of state as applied to mixtures 84 85 Benedict — Webb — Rubin (BWR) equation of state for fugacity coefficients 145 Benedict — Webb — Rubin (BWR) equation of state for thermodynamic departure functions 101—108 Benedict — Webb — Rubin (BWR) equation of state, Lee — Kesler form 36—39 47—49 Benson estimation method for absolute entropy 173—190 Benson estimation method for enthalpy of formation 173—190 Benson estimation method for ideal-gas heat capacity 173—190 Bhirud liquid volume method 67 Binary parameters for regular solution theory 284—289 Blanc’s law 597 Boiling point 25 Boiling point, estimation by Joback method 15 25 Boiling point, table 656—732 Brock and Bird estimation method for pure liquid surface tension 637 Brokaw estimation method for diffusion coefficient of low-pressure gas 584 585 Bruke and Starling estimation method for viscosity of high-pressure gas 430 431 Bruke and Starling estimation method for viscosity of high-temperature liquid 472—473 Bubble point calculations 340 348 349 Bunsen coefficient 332 Cardozo estimation method for enthalpy of combustion 190 191 Cardozo estimation method for enthalpy of formation 190 191 Chemical-theory-based equations of state 351—357 Chen estimation method for enthalpy of vaporization 226 Chueh and Prausnitz estimation method for true critical properties of mixtures, pressure 133 Chueh and Prausnitz estimation method for true critical properties of mixtures, temperature 126—129 Chueh and Prausnitz estimation method for true critical properties of mixtures, volume 129 130 Chueh and Swanson estimation method for liquid heat capacities 138 139 Chung et al. estimation method for thermal conductivity of high-pressure gas 522 523 Chung et al. estimation method for thermal conductivity of high-pressure gas mixture 539 540 Chung et al. estimation method for thermal conductivity of low-pressure gas 504 505 Chung et al. estimation method for viscosity of high-pressure gas 426—430 Chung et al. estimation method for viscosity of high-pressure gas mixture 432 Chung et al. estimation method for viscosity of low-pressure gas 396 397 Chung et al. estimation method for viscosity of low-pressure gas mixture 413—416 Clausius — Clapeyron equation 205 Clausius — Clapeyron equation, integrated form 216 Cohesive energy density 284 Collision integral 392 Collision number 496 Compressed liquid densities 55—66 Compressed liquid densities for mixtures 89 90 Compressibility factor 29—39 Consolute temperature 358 Corresponding states 5 30 140 207 219 221 Critical compressibility factor, table 656—732 Critical points for mixtures from Gibbs criteria 134 135 Critical pressure for mixtures 130—135 Critical pressure, Ambrose estimation method 12—14 212 Critical pressure, Joback estimation method 12 14 15 Critical pressure, table 656—732 Critical temperature for mixtures 126—129 134—135 Critical temperature, Ambrose estimation method 12—14 Critical temperature, Fedors estimation method 14 16 Critical temperature, Joback estimation method 12 14 15 Critical temperature, table 656—732 Critical volume for mixtures 129—130 Critical volume, Ambrose estimation method 12 Critical volume, Joback estimation method 12 14 15 Critical volume, table 656—732 Cubic equations of state 42—46 82—84 102 145 341—350 Darken equation 611 Departure function 97 Deviation function 34 Dew point calculations 340 348—350 Diffusion coefficient for gases, at low pressure, estimation of 581—589 Diffusion coefficient for gases, effect of pressure on 589 592—594 Diffusion coefficient for gases, effect of temperature on 595 596 Diffusion coefficient for gases, multicomponent 596 597 Diffusion coefficient for gases, theory of 577 579 581 Diffusion coefficient for liquids, effect of composition on 611—614 Diffusion coefficient for liquids, effect of solvent viscosity on 606 Diffusion coefficient for liquids, effect of temperature on 614—617 Diffusion coefficient for liquids, electrolyte solutions 620—624 Diffusion coefficient for liquids, estimation of 598—611 Diffusion coefficient for liquids, multicomponent 617—619 Diffusion coefficient for liquids, theory of 597 598 Diffusion coefficient for supercritical fluids 594 Diffusion coefficient, definition of 579 Diffusion coefficient, mutual-, self-, and tracer 580 581 Diffusion coefficient, thermodynamic correction for 581 Diffusivity see “Diffusion coefficient” Dipole moment 26 Dipole moment, table 656—732 Electrolyte solutions, vapor-liquid equilibria 375 Ely and Hanley estimation method for thermal conductivity of high-pressure gas 523—526 Ely and Hanley estimation method for thermal conductivity of high-pressure gas mixture 540—542 Ely and Hanley estimation method for thermal conductivity of low-pressure gas 505—507 Enskog dense-gas theory 418—420 Enthalpy of combustion, Cardozo estimation method 190—191 Enthalpy of formation 150 151 Enthalpy of formation, Benson estimation method 173—190 Enthalpy of formation, Cardozo estimation method 190 191 Enthalpy of formation, Joback estimation method 154—156 Enthalpy of formation, table 656—732 Enthalpy of formation, Thinh et al. estimation method 167—173 Enthalpy of formation, Yoneda estimation method 157—167 Enthalpy of fusion 231 232 Enthalpy of sublimation 222 223 Enthalpy of vaporization from vapor-pressure equations 222—225 Enthalpy of vaporization, at normal boiling point 225—228 Enthalpy of vaporization, effect of temperature on 228 229 Enthalpy of vaporization, Pitzer expansion 220 Enthalpy, departure functions 96—110 Entropy of formation 152 Entropy of vaporization 220 230 231 Entropy, absolute 151 152 Entropy, absolute, Benson estimation method 173—190 Entropy, absolute, Thinh et al. estimation method 167—173 Entropy, absolute, Yoneda estimation method 157—167 Entropy, departure functions 98 100 103 112—115 Equilibrium constant 152 153 Eucken correlation for thermal conductivity of gases 493—495 Eucken factor 493 Excess thermal conductivity 520 Fedors estimation method for critical temperature 14 16 Filippov estimation method for thermal conductivity of liquid mixtures 562 Fish and Lielmezs estimation method for enthalpy of vaporization, temperature effect 229 Flash calculations 340 348—350 Flory — Huggins theory 368—372 Free energy see “Gibbs energy” Freezing point 25 Freezing point, estimation by Joback method 15 25 26 Freezing point, table 656—732 Frost — Kalkwarf — Thodos correlation for vapor pressure 215 Fugacity, coefficient 143—145 339 Fugacity, pressure ratio, equations 99 100 Fugacity, pressure ratio, for a component in a mixture 143—145 Fugacity, pressure ratio, tables 116—119 Fugacity, pure liquid 249—251 Fugacity, standard state 248—250 Fuller et al. estimation method for diffusion coefficients for low-pressure gas 587 588 Giacalone estimation method for enthalpy of vaporization 225 Gibbs energy of formation 152 153 201 Gibbs energy of formation, Joback estimation method 154—156 Gibbs energy of formation, table 656—732 Gibbs energy of formation, Thinh et al. estimation method 167—173 Gibbs energy, departure functions 98 100 Gibbs energy, excess, relation to activity coefficient 251—253 Gibbs — Duhem equation 251 252 Gmehling equation of state 352—357 Gomez — Thodos vapor pressure equation 209—212 Gordon estimation method for diffusion coefficient in electrolyte solutions 621 Grunberg and Nissan estimation method for liquid mixture viscosity 474—478 Hakim, Steinberg, and Stiel estimation method for surface tension 638 Hankinson — Brobst — Thomson liquid volume method 55—66 Hankinson — Brobst — Thomson liquid volume method for mixtures 89 90 Hayduk and Minhas estimation method for diffusion coefficient of liquid 602 603 Heat capacity of gases 121 Heat capacity of gases, departure functions 122—125 Heat capacity of ideal gas 151 152 Heat capacity of ideal gas, Benson estimation method 173—190 Heat capacity of ideal gas, Joback estimation method 154—156 Heat capacity of ideal gas, table 656—732 Heat capacity of ideal gas, Thinh et al. estimation method 167—173 Heat capacity of ideal gas, Yoneda estimation method 157—167 Heat capacity of liquids 136—143 Heat capacity of liquids, corresponding states estimation methods 140—141 Heat capacity of liquids, definitions of 136 Heat capacity of liquids, group contribution estimation methods 137—140 Heat of formation see “Enthalpy of formation” Heat of vaporization see “Enthalpy of vaporization” Heidemann method for mixture critical points 134 135 Helmholtz energy, departure functions 98 100 Henry’s law 334 337 Herning and Zipperer estimation method for the viscosity of low-pressure gas mixtures 410 411 Ideal gas 29 30 151 152 Ideal reduced volume 31—33 47 Internal energy, departure functions 98 100 Isomer correction 188 189 Jamieson et al. estimation technique for thermal conductivity of liquid mixtures 562 Joback estimation method for boiling point 15 25 Joback estimation method for critical properties 12 14 15 Joback estimation method for enthalpy of formation 154—156 Joback estimation method for freezing point 15 25 26 Joback estimation method for Gibbs energy of formation 154—156 Joback estimation method for ideal-gas heat capacity 154—156 Jossi, Stiel and Thodos estimation method for viscosity of high-pressure gas 424—426 Kay’s rule for pseudocritical properties 76 Kinematic viscosity 389 435 Kinetic theory of gases to estimate transport properties 390 391 Kreglewski and Kay estimation method for true critical pressure of mixtures 131—133 Latini et al. estimation method for the effect of pressure on thermal conductivity of liquids 560 Latini et al. estimation method for thermal conductivity of liquids 549 550 Law of corresponding states see “Corresponding states” Le Bas estimation method for molar volumes of liquids at the normal boiling point 53 54 Lee — Kesler estimation method for acentric factor 23 24 Lee — Kesler estimation method for compressibility factors 36—39 47—49 Lee — Kesler estimation method for gas-heat capacity 122—125 Lee — Kesler estimation method for thermodynamic departure functions 101—107 112—119 121—125 Lee — Kesler estimation method for vapor pressures 207 Lee — Kesler estimation method for vapor-liquid equilibria 341 Lennard-Jones potential 392 393 582 583 Lennard-Jones potential, parameters 733 734 Lenoir correlation for pressure effect on thermal conductivity of liquids 558 Letsou and Stiel estimation method for viscosity of high-temperature liquid 471 Lewis and Squires correlation for liquid viscosity with temperature 439 440 Lewis fugacity rule 277 335 Li estimation method for thermal conductivity of liquid mixtures 565 Li estimation method for true critical temperature of mixtures 126 Liquid densities 52—68 Liquid heat capacities 136—143 Liquid mixtures, mixing rules for 89—91 Liquid molar volume at normal boiling point 52—55 Liquid-liquid equilibria 309—311 357—368 Local composition mixing rules 87—89 351 Lucas estimation method for viscosity of high-pressure gas 421—424 Lucas estimation method for viscosity of high-pressure gas mixture 431 432 Lucas estimation method for viscosity of high-pressure liquid 436—438 Lucas estimation method for viscosity of low-pressure gas 397 400 401 Lucas estimation method for viscosity of low-pressure gas mixture 411 412 MacLeod and Sugden estimation method for surface tension, liquid mixtures 642 643 MacLeod and Sugden estimation method for surface tension, pure liquids 633—637 Margules correlation for activity coefficients 254—257 Mason and Monchick equation for thermal conductivity of polyatomic gases 495—498 Mason and Saxena estimation method for thermal conductivity of low-pressure gas mixtures 531 532 Maximum likelihood method 270 271 Melting point see “Freezing point” Michelson method for mixture critical points 134 135 Miller vapor pressure equation 215 Missenard estimation method, heat capacity of liquid 139 Missenard estimation method, thermal conductivity of liquid 552 Missenard estimation method, thermal conductivity of liquid, effect of pressure on 559 Mixing rules 75—91 MOSCED method for infinite dilution activity coefficients 299—307 Mutual diffusion coefficient 580 581 Nakanishi estimation method for diffusion coefficient of liquids 604 605 Nelson and Obert charts to estimate compressibility factors 31 32 NRTL correlation for activity coefficients 254—257 274 361—364 Orrick and Erbar estimation method for viscosity of liquids 456 458 Ostwald coefficient 332 Parachor 600 601 636 642 Peneloux correction to SRK equation 45 84 Peng — Robinson equation of state 42 43 Peng — Robinson equation of state, departure functions 102 Peng — Robinson equation of state, fugacity coefficients 145 Peng — Robinson equation of state, mixing rules 82—84 88 Peng — Robinson equation of state, vapor-liquid equilibria 341 Perkins and Geankoplis estimation method for diffusion coefficient in homogeneous, multicomponent liquid mixtures 617 618 Phase envelope construction 348 Phase equilibria in polymer solutions 368—372 Phase equilibria of aqueous solutions of electrolytes 375—379 Phase equilibria of gases in liquids 332—337 Phase equilibria of solids in liquids 372—375 Phase equilibria, basic equations 247 Phase equilibria, calculation of 259—262 Phase equilibria, effect of temperature on 262—264 Phase equilibria, high-pressure 337—357 Phase equilibria, liquid-liquid 357—368 Phase equilibria, multicomponent 273—274 Phase equilibria, reference texts, table 242—246 333 377 Phase equilibria, statistical analysis 270—271 Phase equilibria, with activity coefficients 247—332 Phase equilibria, with equations of state 337—357 366 367 Phase splitting 357 358 Piatt number, table 14 Pitzer — Curl expansion for compressibility factors 36—39 Pitzer — Curl expansion for enthalpy departure functions 102 104—107 Pitzer — Curl expansion for entropy departure functions 103 112—115 Pitzer — Curl expansion for entropy of vaporization 220 Pitzer — Curl expansion for fugacity-pressure ratios 103 116—119 Pitzer — Curl expansion for heat capacity departure functions 121—125 Pitzer — Curl expansion for vapor pressure 207 Polymer solutions, phase equilibria in 368—372 Poynting factor 250 Prausnitz and Gunn rules to estimate pseudocritical properties 77 Property data bank 656—732 Przezdziecki and Sridhar estimation method for viscosity of liquids 465 468 469 Pseudocritical properties 76—79 Rackett compressibility factor 45 46 Rackett compressibility factor for mixtures 89 Rackett equation for estimating liquid volumes 67 Raoult’s Law 251 Redlich-Kwong equation of state as applied to mixtures 82—84 Redlich-Kwong equation of state for fugacity coefficients 145 Redlich-Kwong equation of state for gas-phase volumetric properties 43 Redlich-Kwong equation of state for thermodynamic departure functions 102
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