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Reid R.C., Prausnitz J.M., Poling B.E. — The Properties of Gases and Liquids
Reid R.C., Prausnitz J.M., Poling B.E. — The Properties of Gases and Liquids



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Íàçâàíèå: The Properties of Gases and Liquids

Àâòîðû: Reid R.C., Prausnitz J.M., Poling B.E.

Àííîòàöèÿ:

Completely rewritten and reorganized to reflect the latest developments in estimating the properties of gases and liquids, this new edition of the highly regarded reference presents a comprehensive survey of the most reliable estimation methods in use today. It provides instantly usable information on estimating both physical and thermodynamic properties when experimental data are not available (for example, constants such as critical temperature, critical pressure, acentric factor, and others); thermodynamic properties of gases and liquids, both pure and mixtures, including enthalpies, entropies, fugacity coefficients, heat capacities, and critical points; vapor-liquid and liquid-liquid equilibria as needed in separation operations such as distillation, absorption, and extraction. An invaluable reference that provides property values for more than 600 pure chemicals, this is the only book in its field to include a critical analysis of existing methods as well as practical recommendations.


ßçûê: en

Ðóáðèêà: Ôèçèêà/

Ñòàòóñ ïðåäìåòíîãî óêàçàòåëÿ: Ãîòîâ óêàçàòåëü ñ íîìåðàìè ñòðàíèö

ed2k: ed2k stats

Èçäàíèå: fourth edition

Ãîä èçäàíèÿ: 1987

Êîëè÷åñòâî ñòðàíèö: 741

Äîáàâëåíà â êàòàëîã: 23.03.2006

Îïåðàöèè: Ïîëîæèòü íà ïîëêó | Ñêîïèðîâàòü ññûëêó äëÿ ôîðóìà | Ñêîïèðîâàòü ID
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Ïðåäìåòíûé óêàçàòåëü
Acentric factor      23 24 34
Acentric factor, table      656—732
Activity coefficients from ASOG group contribution method      313—314
Activity coefficients from azeotropic data      307—309
Activity coefficients from mutual solubilities      309—311
Activity coefficients from UNIFAC group contribution method      314—332
Activity coefficients, at infinite dilution      290—307
Activity coefficients, correlations for      254—257
Activity coefficients, definition of      248
Activity coefficients, estimation of      283—332
Activity coefficients, one-parameter correlations for      255—259
Ambrose estimation method for critical properties      12—14
Amoco Redlich-Kwong equation of state      44 346
Andrade correlation for liquid viscosity      439
Antoine vapor pressure equation      208 209
Aqueous solutions of electrolytes, phase equilibria of      375—379
ASOG (analytical solution of groups) group contribution method for activity coefficients      313—314
Athermal solution      262
Barker’s method for phase equilibrium calculations      272
Barner and Quinlan values      78 79
Barner and Quinlan values for Lee — Kesler equation      85—87 343
Barner and Quinlan values for Peng — Robinson equation      83 343
Barner and Quinlan values for Soave equation      83 343
Baroncini et al. estimation method for thermal conductivity of liquid mixtures      562 563
Benedict — Webb — Rubin (BWR) equation of state as applied to mixtures      84 85
Benedict — Webb — Rubin (BWR) equation of state for fugacity coefficients      145
Benedict — Webb — Rubin (BWR) equation of state for thermodynamic departure functions      101—108
Benedict — Webb — Rubin (BWR) equation of state, Lee — Kesler form      36—39 47—49
Benson estimation method for absolute entropy      173—190
Benson estimation method for enthalpy of formation      173—190
Benson estimation method for ideal-gas heat capacity      173—190
Bhirud liquid volume method      67
Binary parameters for regular solution theory      284—289
Blanc’s law      597
Boiling point      25
Boiling point, estimation by Joback method      15 25
Boiling point, table      656—732
Brock and Bird estimation method for pure liquid surface tension      637
Brokaw estimation method for diffusion coefficient of low-pressure gas      584 585
Bruke and Starling estimation method for viscosity of high-pressure gas      430 431
Bruke and Starling estimation method for viscosity of high-temperature liquid      472—473
Bubble point calculations      340 348 349
Bunsen coefficient      332
Cardozo estimation method for enthalpy of combustion      190 191
Cardozo estimation method for enthalpy of formation      190 191
Chemical-theory-based equations of state      351—357
Chen estimation method for enthalpy of vaporization      226
Chueh and Prausnitz estimation method for true critical properties of mixtures, pressure      133
Chueh and Prausnitz estimation method for true critical properties of mixtures, temperature      126—129
Chueh and Prausnitz estimation method for true critical properties of mixtures, volume      129 130
Chueh and Swanson estimation method for liquid heat capacities      138 139
Chung et al. estimation method for thermal conductivity of high-pressure gas      522 523
Chung et al. estimation method for thermal conductivity of high-pressure gas mixture      539 540
Chung et al. estimation method for thermal conductivity of low-pressure gas      504 505
Chung et al. estimation method for viscosity of high-pressure gas      426—430
Chung et al. estimation method for viscosity of high-pressure gas mixture      432
Chung et al. estimation method for viscosity of low-pressure gas      396 397
Chung et al. estimation method for viscosity of low-pressure gas mixture      413—416
Clausius — Clapeyron equation      205
Clausius — Clapeyron equation, integrated form      216
Cohesive energy density      284
Collision integral      392
Collision number      496
Compressed liquid densities      55—66
Compressed liquid densities for mixtures      89 90
Compressibility factor      29—39
Consolute temperature      358
Corresponding states      5 30 140 207 219 221
Critical compressibility factor, table      656—732
Critical points for mixtures from Gibbs criteria      134 135
Critical pressure for mixtures      130—135
Critical pressure, Ambrose estimation method      12—14 212
Critical pressure, Joback estimation method      12 14 15
Critical pressure, table      656—732
Critical temperature for mixtures      126—129 134—135
Critical temperature, Ambrose estimation method      12—14
Critical temperature, Fedors estimation method      14 16
Critical temperature, Joback estimation method      12 14 15
Critical temperature, table      656—732
Critical volume for mixtures      129—130
Critical volume, Ambrose estimation method      12
Critical volume, Joback estimation method      12 14 15
Critical volume, table      656—732
Cubic equations of state      42—46 82—84 102 145 341—350
Darken equation      611
Departure function      97
Deviation function      34
Dew point calculations      340 348—350
Diffusion coefficient for gases, at low pressure, estimation of      581—589
Diffusion coefficient for gases, effect of pressure on      589 592—594
Diffusion coefficient for gases, effect of temperature on      595 596
Diffusion coefficient for gases, multicomponent      596 597
Diffusion coefficient for gases, theory of      577 579 581
Diffusion coefficient for liquids, effect of composition on      611—614
Diffusion coefficient for liquids, effect of solvent viscosity on      606
Diffusion coefficient for liquids, effect of temperature on      614—617
Diffusion coefficient for liquids, electrolyte solutions      620—624
Diffusion coefficient for liquids, estimation of      598—611
Diffusion coefficient for liquids, multicomponent      617—619
Diffusion coefficient for liquids, theory of      597 598
Diffusion coefficient for supercritical fluids      594
Diffusion coefficient, definition of      579
Diffusion coefficient, mutual-, self-, and tracer      580 581
Diffusion coefficient, thermodynamic correction for      581
Diffusivity      see “Diffusion coefficient”
Dipole moment      26
Dipole moment, table      656—732
Electrolyte solutions, vapor-liquid equilibria      375
Ely and Hanley estimation method for thermal conductivity of high-pressure gas      523—526
Ely and Hanley estimation method for thermal conductivity of high-pressure gas mixture      540—542
Ely and Hanley estimation method for thermal conductivity of low-pressure gas      505—507
Enskog dense-gas theory      418—420
Enthalpy of combustion, Cardozo estimation method      190—191
Enthalpy of formation      150 151
Enthalpy of formation, Benson estimation method      173—190
Enthalpy of formation, Cardozo estimation method      190 191
Enthalpy of formation, Joback estimation method      154—156
Enthalpy of formation, table      656—732
Enthalpy of formation, Thinh et al. estimation method      167—173
Enthalpy of formation, Yoneda estimation method      157—167
Enthalpy of fusion      231 232
Enthalpy of sublimation      222 223
Enthalpy of vaporization from vapor-pressure equations      222—225
Enthalpy of vaporization, at normal boiling point      225—228
Enthalpy of vaporization, effect of temperature on      228 229
Enthalpy of vaporization, Pitzer expansion      220
Enthalpy, departure functions      96—110
Entropy of formation      152
Entropy of vaporization      220 230 231
Entropy, absolute      151 152
Entropy, absolute, Benson estimation method      173—190
Entropy, absolute, Thinh et al. estimation method      167—173
Entropy, absolute, Yoneda estimation method      157—167
Entropy, departure functions      98 100 103 112—115
Equilibrium constant      152 153
Eucken correlation for thermal conductivity of gases      493—495
Eucken factor      493
Excess thermal conductivity      520
Fedors estimation method for critical temperature      14 16
Filippov estimation method for thermal conductivity of liquid mixtures      562
Fish and Lielmezs estimation method for enthalpy of vaporization, temperature effect      229
Flash calculations      340 348—350
Flory — Huggins theory      368—372
Free energy      see “Gibbs energy”
Freezing point      25
Freezing point, estimation by Joback method      15 25 26
Freezing point, table      656—732
Frost — Kalkwarf — Thodos correlation for vapor pressure      215
Fugacity, coefficient      143—145 339
Fugacity, pressure ratio, equations      99 100
Fugacity, pressure ratio, for a component in a mixture      143—145
Fugacity, pressure ratio, tables      116—119
Fugacity, pure liquid      249—251
Fugacity, standard state      248—250
Fuller et al. estimation method for diffusion coefficients for low-pressure gas      587 588
Giacalone estimation method for enthalpy of vaporization      225
Gibbs energy of formation      152 153 201
Gibbs energy of formation, Joback estimation method      154—156
Gibbs energy of formation, table      656—732
Gibbs energy of formation, Thinh et al. estimation method      167—173
Gibbs energy, departure functions      98 100
Gibbs energy, excess, relation to activity coefficient      251—253
Gibbs — Duhem equation      251 252
Gmehling equation of state      352—357
Gomez — Thodos vapor pressure equation      209—212
Gordon estimation method for diffusion coefficient in electrolyte solutions      621
Grunberg and Nissan estimation method for liquid mixture viscosity      474—478
Hakim, Steinberg, and Stiel estimation method for surface tension      638
Hankinson — Brobst — Thomson liquid volume method      55—66
Hankinson — Brobst — Thomson liquid volume method for mixtures      89 90
Hayduk and Minhas estimation method for diffusion coefficient of liquid      602 603
Heat capacity of gases      121
Heat capacity of gases, departure functions      122—125
Heat capacity of ideal gas      151 152
Heat capacity of ideal gas, Benson estimation method      173—190
Heat capacity of ideal gas, Joback estimation method      154—156
Heat capacity of ideal gas, table      656—732
Heat capacity of ideal gas, Thinh et al. estimation method      167—173
Heat capacity of ideal gas, Yoneda estimation method      157—167
Heat capacity of liquids      136—143
Heat capacity of liquids, corresponding states estimation methods      140—141
Heat capacity of liquids, definitions of      136
Heat capacity of liquids, group contribution estimation methods      137—140
Heat of formation      see “Enthalpy of formation”
Heat of vaporization      see “Enthalpy of vaporization”
Heidemann method for mixture critical points      134 135
Helmholtz energy, departure functions      98 100
Henry’s law      334 337
Herning and Zipperer estimation method for the viscosity of low-pressure gas mixtures      410 411
Ideal gas      29 30 151 152
Ideal reduced volume      31—33 47
Internal energy, departure functions      98 100
Isomer correction      188 189
Jamieson et al. estimation technique for thermal conductivity of liquid mixtures      562
Joback estimation method for boiling point      15 25
Joback estimation method for critical properties      12 14 15
Joback estimation method for enthalpy of formation      154—156
Joback estimation method for freezing point      15 25 26
Joback estimation method for Gibbs energy of formation      154—156
Joback estimation method for ideal-gas heat capacity      154—156
Jossi, Stiel and Thodos estimation method for viscosity of high-pressure gas      424—426
Kay’s rule for pseudocritical properties      76
Kinematic viscosity      389 435
Kinetic theory of gases to estimate transport properties      390 391
Kreglewski and Kay estimation method for true critical pressure of mixtures      131—133
Latini et al. estimation method for the effect of pressure on thermal conductivity of liquids      560
Latini et al. estimation method for thermal conductivity of liquids      549 550
Law of corresponding states      see “Corresponding states”
Le Bas estimation method for molar volumes of liquids at the normal boiling point      53 54
Lee — Kesler estimation method for acentric factor      23 24
Lee — Kesler estimation method for compressibility factors      36—39 47—49
Lee — Kesler estimation method for gas-heat capacity      122—125
Lee — Kesler estimation method for thermodynamic departure functions      101—107 112—119 121—125
Lee — Kesler estimation method for vapor pressures      207
Lee — Kesler estimation method for vapor-liquid equilibria      341
Lennard-Jones potential      392 393 582 583
Lennard-Jones potential, parameters      733 734
Lenoir correlation for pressure effect on thermal conductivity of liquids      558
Letsou and Stiel estimation method for viscosity of high-temperature liquid      471
Lewis and Squires correlation for liquid viscosity with temperature      439 440
Lewis fugacity rule      277 335
Li estimation method for thermal conductivity of liquid mixtures      565
Li estimation method for true critical temperature of mixtures      126
Liquid densities      52—68
Liquid heat capacities      136—143
Liquid mixtures, mixing rules for      89—91
Liquid molar volume at normal boiling point      52—55
Liquid-liquid equilibria      309—311 357—368
Local composition mixing rules      87—89 351
Lucas estimation method for viscosity of high-pressure gas      421—424
Lucas estimation method for viscosity of high-pressure gas mixture      431 432
Lucas estimation method for viscosity of high-pressure liquid      436—438
Lucas estimation method for viscosity of low-pressure gas      397 400 401
Lucas estimation method for viscosity of low-pressure gas mixture      411 412
MacLeod and Sugden estimation method for surface tension, liquid mixtures      642 643
MacLeod and Sugden estimation method for surface tension, pure liquids      633—637
Margules correlation for activity coefficients      254—257
Mason and Monchick equation for thermal conductivity of polyatomic gases      495—498
Mason and Saxena estimation method for thermal conductivity of low-pressure gas mixtures      531 532
Maximum likelihood method      270 271
Melting point      see “Freezing point”
Michelson method for mixture critical points      134 135
Miller vapor pressure equation      215
Missenard estimation method, heat capacity of liquid      139
Missenard estimation method, thermal conductivity of liquid      552
Missenard estimation method, thermal conductivity of liquid, effect of pressure on      559
Mixing rules      75—91
MOSCED method for infinite dilution activity coefficients      299—307
Mutual diffusion coefficient      580 581
Nakanishi estimation method for diffusion coefficient of liquids      604 605
Nelson and Obert charts to estimate compressibility factors      31 32
NRTL correlation for activity coefficients      254—257 274 361—364
Orrick and Erbar estimation method for viscosity of liquids      456 458
Ostwald coefficient      332
Parachor      600 601 636 642
Peneloux correction to SRK equation      45 84
Peng — Robinson equation of state      42 43
Peng — Robinson equation of state, departure functions      102
Peng — Robinson equation of state, fugacity coefficients      145
Peng — Robinson equation of state, mixing rules      82—84 88
Peng — Robinson equation of state, vapor-liquid equilibria      341
Perkins and Geankoplis estimation method for diffusion coefficient in homogeneous, multicomponent liquid mixtures      617 618
Phase envelope construction      348
Phase equilibria in polymer solutions      368—372
Phase equilibria of aqueous solutions of electrolytes      375—379
Phase equilibria of gases in liquids      332—337
Phase equilibria of solids in liquids      372—375
Phase equilibria, basic equations      247
Phase equilibria, calculation of      259—262
Phase equilibria, effect of temperature on      262—264
Phase equilibria, high-pressure      337—357
Phase equilibria, liquid-liquid      357—368
Phase equilibria, multicomponent      273—274
Phase equilibria, reference texts, table      242—246 333 377
Phase equilibria, statistical analysis      270—271
Phase equilibria, with activity coefficients      247—332
Phase equilibria, with equations of state      337—357 366 367
Phase splitting      357 358
Piatt number, table      14
Pitzer — Curl expansion for compressibility factors      36—39
Pitzer — Curl expansion for enthalpy departure functions      102 104—107
Pitzer — Curl expansion for entropy departure functions      103 112—115
Pitzer — Curl expansion for entropy of vaporization      220
Pitzer — Curl expansion for fugacity-pressure ratios      103 116—119
Pitzer — Curl expansion for heat capacity departure functions      121—125
Pitzer — Curl expansion for vapor pressure      207
Polymer solutions, phase equilibria in      368—372
Poynting factor      250
Prausnitz and Gunn rules to estimate pseudocritical properties      77
Property data bank      656—732
Przezdziecki and Sridhar estimation method for viscosity of liquids      465 468 469
Pseudocritical properties      76—79
Rackett compressibility factor      45 46
Rackett compressibility factor for mixtures      89
Rackett equation for estimating liquid volumes      67
Raoult’s Law      251
Redlich-Kwong equation of state as applied to mixtures      82—84
Redlich-Kwong equation of state for fugacity coefficients      145
Redlich-Kwong equation of state for gas-phase volumetric properties      43
Redlich-Kwong equation of state for thermodynamic departure functions      102
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