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Rushbrooke G.S. — Introduction to Statistical Mechanics
Rushbrooke G.S. — Introduction to Statistical Mechanics



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Название: Introduction to Statistical Mechanics

Автор: Rushbrooke G.S.

Аннотация:

Statistical mechanics or statistical thermodynamics is a branch of physics that applies probability theory, which contains mathematical tools for dealing with large populations, to the study of the thermodynamic behavior of systems composed of a large number of particles. Statistical mechanics provides a framework for relating the microscopic properties of individual atoms and molecules to the macroscopic bulk properties of materials that can be observed in everyday life, thereby explaining thermodynamics as a result of the classical- and quantum-mechanical descriptions of statistics and mechanics at the microscopic level.


Язык: en

Рубрика: Механика/

Статус предметного указателя: Готов указатель с номерами страниц

ed2k: ed2k stats

Год издания: 1949

Количество страниц: 347

Добавлена в каталог: 15.04.2013

Операции: Положить на полку | Скопировать ссылку для форума | Скопировать ID
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Предметный указатель
Adsorption with dissociation      217
Adsorption, Fowler's isotherm      310
Adsorption, Langmuir's isotherm      214 217 249 286 288 317
Anharmonioity      115
Band spectra      114
Boltzmann's constant      7 12 49 124
Boltzmann's H-theorem      314
Bragg and Williams approximation      294 309
Chemical potential of condensed phase      35
Chemical potential of monatomic gas      49
Chemical potential of perfeot gas      50 190
Chemical potential, and law of mass action      187
Classical statistics, condition for      46
Conversion factors      121
Critical adsorption      310
Critical mixing temperature      296 306 307
Darwin — Fowler method      312
Debye, specific heat of solid      34 140 147
Definitions, absolute activity      196
Definitions, assembly      4
Definitions, calorimetric entropy      138
Definitions, characteristic temperature      93
Definitions, classical statistics      46
Definitions, complexion      11
Definitions, component      5
Definitions, degenerate gas      46
Definitions, distribution numbers      17
Definitions, Einstein model      198
Definitions, ensemble      236
Definitions, equilibrium constant      186
Definitions, equilibrium constant, set of distribution numbers      22
Definitions, grand partition function      274
Definitions, independent systems      15
Definitions, internal distribution function      74
Definitions, localized systems      15
Definitions, metastable equilibrium      109
Definitions, non-localized systems      36
Definitions, partition function, assembly      237
Definitions, partition function, system      24 40 59
Definitions, perfect solution      226
Definitions, phase integral      60
Definitions, phase integral, space      56
Definitions, practical entropy      144
Definitions, quantal statistics      46
Definitions, regular solution      291
Definitions, representative point      56
Definitions, restrictive condition      17
Definitions, species      5
Definitions, spectroscopic entropy      168
Definitions, symmetry factor      88
Definitions, system      4
Definitions, thermodynamic method (for polyphase assemblies)      205
Definitions, weight factor      25
Dieleotric constant of gases      165
Dimerization, in condensed phase      214 286
Dimerization, in solution      230 286
Dipole moments      167
Dissociative equilibrium, gas phase, A+A = $A_{2}$      194 284
Dissociative equilibrium, gas phase, A+B = AB      178 282
Dissociative equilibrium, gas phase, AB+CD = AC+BD      197
Dissociative equilibrium, gas phase, general      196 284
Doppler broadening      78
Duhem — Margules equation      230 234 310 327
Dulong and Petit, law of      33 65
Einstein model      198 214 218 224 279 284 289 315
Einstein — Bose statistics      45 63 286
Einstein, specific heat of solid      30
Energy, classical law      66 70
Entropy of assembly      249
Entropy of mixing, of gases      176 186
Entropy of perfect solutions      229 234
Entropy of polyatomic rigid molecules      135
Entropy, and disorder      8
Entropy, rotational, of diatomic molecule      98 154
Entropy, rotational, of rigid molecule      153 154
Entropy, translational      48
Entropy, vibrational      35 97
Eulerian angles      131 157
Fermi — Dirac statistics      45 63 286
Fluctuation effects      2 28
Gibbs paradox      177
Gibbs — Helmholtz formula      32 237 302 318
Grand partition function for [1]-regular solution      299
Grand partition function, defined      274
Grand partition function, references      332
Grand partition function, table of      286
Guggenheim's equation of quasi-chemical equilibrium      300 310
Heisenberg's uncertainty relation      55
Hindered rotation      150
Imperfect gas      46 250 281
Imperfect mixture      270
Intensity of spectral lines      116
Internal distribution functions      9 81
Internal distribution functions, linear rotator      117
Internal distribution functions, Maxwell — Boltzmann law      78
Internal distribution functions, ortho-para-hydrogen ratio      103
Internal distribution functions, polar gases in external field      156
Internal distribution functions, [1]-harmonic oscillators, classical      76
Internal distribution functions, [1]-harmonic oscillators, quantal      75
Internal distribution functions, [2]- and [3]-harmonic oscillators      83
Ising model      296
Isotopes      144
Lagrange's undetermined multipliers      19 207 273 324
Langevin function      162
Law of mass action, condensed phase      217
Law of mass action, gas phase      185 282
Maxwell — Boltzmann law      78 83
Metastable equilibrium      109 141
Multinomial theorem      243 322
Nernst's law      136 143
Non-rigid molecules      149 309
Nuclear spin      101 143
Partition function for assembly, defined      237
Partition function for assembly, imperfect gas      265
Partition function for assembly, independent localized systems      244
Partition function for assembly, independent non-localized systems      246 252
Partition function for assembly, perfect solution      289
Partition function for assembly, regular solution      291
Partition function, defined      24 40 59
Partition function, diatomic gas, classical      89
Partition function, diatomic gas, classical, quantal      93
Partition function, electronic (in molecule)      96
Partition function, factorization property of      80 248
Partition function, monatomic gas      127
Partition function, orientational-rotational      157
Partition function, rotation of diatomic molecule, classical      88
Partition function, rotation of diatomic molecule, classical, quantal      91
Partition function, rotation of diatomic molecule, deuterium      110
Partition function, rotation of diatomic molecule, hydrogen      102
Partition function, rotation of diatomic molecule, rigid moleoule      130
Partition function, translational, classical treatment      63
Partition function, translational, numerical value      53
Partition function, translational, quantal treatment      43
Partition function, [1]-harmonic oscillator, classical      65
Partition function, [1]-harmonic oscillator, classical, quantal      32 63
Partition function, [1]-rotator      152 154
Partition function, [2]-harmonic oscillator      35
Partition function, [3]-harmonic oscillator      32
Perfect gas      51
Phase separation      296 306 327
Physioal constants      121 330
Polarizability      165
Polymers      309
Raoult's law      227 282 287
Rotational levels and selection rules      113
Sackur — Tetrode equation      48 136 146 154 176
Specific heat, diatomic gas, classical      89
Specific heat, diatomic gas, classical, quantal      92 94
Specific heat, electronic (in molecules)      95
Specific heat, equilibrium hydrogen      105
Specific heat, hindered rotation      152
Specific heat, hydrogen      90
Specific heat, monatomic gas      48
Specific heat, ortho- and para-hydrogen      99
Specific heat, polyatomic rigid molecules      134
Specific heat, solid      30
Specific heat, vibrational      97
Stirling's formula      20 28 245 310 326
Temperature-dependent energy levels      316
Translational energy levels      40
Van der Waals' equation      268
Vibrational levels and selection rules      113 115
Vibrations of polyatomic molecule      128
Virial expansion      259 267 270
Virial expansion for mixture      271
Volume of condensed phase, effect of      209 284
Zero-point energy      31 76
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