Chivers T. — A Guide to Chalcogen-Nitrogen Chemistry :: Электронная библиотека попечительского совета мехмата МГУ

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Chivers T. — A Guide to Chalcogen-Nitrogen Chemistry

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Название: A Guide to Chalcogen-Nitrogen Chemistry

Автор: Chivers T.

Аннотация:

A Guide to Chalcogen-Nitrogen Chemistry examines the role of chalcogen-nitrogen compounds in areas ranging from solid-state inorganic chemistry to biochemistry. The discussion covers fundamental questions concerning the bonding in electron-rich systems, as well as potential practical applications of polymers and materials with novel magnetic or electrical properties. This book is the only account of this important topic to appear in the last twenty-five years, and coupled with its extensive literature coverage of very recent developments, this comprehensive guide is essential for anyone working in the field. The treatment is unique in providing a comparison of sulfur, selenium and tellurium systems, with an approach intended to emphasize general concepts that will be helpful to the non-specialist. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.

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Рубрика: Химия/

Статус предметного указателя: Готов указатель с номерами страниц

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Год издания: 2005

Количество страниц: 318

Добавлена в каталог: 18.03.2006

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Предметный указатель

ring      267
ring      213
rings      22
ring      267
ring      270
ring      26 267
$[Et_4P_2N_4S_2]^{2+}$ dication      263
$[Ph_4P_2N_4S_2]^{2-}$ dianion      263—265
$[Te_2S_2N_4]^{2+}$ dication      155
$^{15}N$ -enriched       23
$^{15}N$ -enriched       100
$^{15}N$ -enrichment, $S_4^{15}N_4$       47
$^{15}N$ -labelled S-N compounds      19
$^{15}N-^{15}N$ coupling      34
${\mu}_3$ -Nitrido      155
1,2,3,4-Trithiazolium radical cations      224
1,2,3,5-Dithiadiazolium cation      214—216
1,2,3,5-Dithiadiazolyl radicals      67 217—220
1,2,3,5-Dithiadiazolyls      67
1,2,3-Dithiazolium      224
1,2,3-Dithiazolyls      226
1,2,3-Selenadiazole      232
1,2,5-Selenadiazole      228 231
1,2,5-Telluradiazole      229—231
1,2,5-Thiadiazoles      88 228 230 231
1,2-Selenazine      182
1,3,2,4-Dithiadiazolium cation      221
1,3,2,4-Dithiadiazolyl radicals      222
1,3,2-Dithiazolium      226
1,3,2-Dithiazolyls      67 226
1,3-Metallotropic shift      265
1,3-Nitrogen shifts      34 74 75 254
2-Selenobenzylamine      298
5-Oxo-1,3,2,4-dithiadiazole,       223
Acyclic cation,       147
Acyclic cation,       147
Acyclic cation,       147
Allylic amination      185
Anion,       143
Anion,       142
Anion, , complex      132
Anion, $[N_3Se_3O_6]^{3-}$       175
Anion,       154
Anion, $[N_3S_3O_6]^{3-}$       175
Anion, $[Se_2N_2]^{2-}$ , complexes      128
Anion, , complexes      129
Anion,       see “Thionitrite”
Anion, , complexes      131
Anion, $[SN_2]^{2-}$       98 99
Anion, $[SN_2]^{2-}$ , complexes      136
Anion,       165
Anion,       165
Anion,       see “Perthionitrite”
Anion,       100
Anion,       100
Anion, , complexes      128
Anion,       101
Anion, , complexes      127
Anion, $[S_2N_2]^{2-}$ , complexes      128
Anion, $[S_2N_3]^{3-}$ , complexes      130
Anion,       174
Anion,       174
Anion,       174
Anion,       102
Anion, $[S_3N_4]^{2-}$ , complexes      130
Anion, , complexes      130
Anion, $[S_4N_4]^{2-}$ , complexes      130
Anion,       175
Anion,       175
Anion,       103
Anomeric effect      150 245
Antiaromatic systems      61
Antimony derivatives      266
Aromaticity      58 60
Arsenic derivative,       265
Arylselenium azides      23 306
Atacticity      290
Azadisulfite dianion      171
Azasulfite anions      171
Benzenesulfinyl azide,       202
Benzo-1,2,3-thiadiazole      231
Benzo-1,2,5-selenadiazole      228
Benzo-1,2,5-telluradiazoles      229
Benzo-1,2,5-thiadiazole      231
Benzo-1,3,2-dithiazolyl      201
Benzodithiadiazine      245 246
Benzotrithiadiazepine      247
Bicyclic compound,       261
Bicyclic ring,       253 254
Bis(sulfinylamino)selane,       166
Bis(sulfinylamino)sulfane,       166
Bis(sulfinylamino)tellane,       166
Bistability      227
Chalcogen-nitrogen bonds, formation      18—28
Chiral organoselenyl halides      306
Conducting polymers      280
Conductivity,       56
Covalent radii      2
Cyanuric-sulfanuric system      243 251
Cyanuric-thiazyl system      242
Cyclic chalcogen imides      3 4 111—119
Cyclic selenium imides      117—119
Cyclic sulfur imides      112—117
Cyclic tellurium imide,       117
Cycloaddition      69—71
Cycloaddition, NSF      142
Cyclocondensation      18 22 24 262
Cyclometallathiazenes      125—129 167 265
Cyclopentathiazyl cation,       97
Cyclophosphadithiatriazines,       260 261
Cyclotetrathiazene dioxide,       174
Cyclotetrathiazyl dication, $[S_4N_4]^{2+}$       96
Cyclotetrathiazyl fluoride,       152
Cyclotrithiazyl cation,       95
Cyclotrithiazyl chloride,       149—152
Cyclotrithiazyl fluoride,       149—150
Diaminopolyselanes,       199
Diaminoselanes,       199
Diaminosulfanes,       199
Diaminotellanes,       31 199
Diazasulfite anions      170
Dibenzenesulfenamino radical, $[(PhS)_2N]^{\bullet}$       202
Diels — Alder      182 248
Diffraction techniques      33—36
Dihalocyclotetrathiazenes      152
Dinitrogen sulfide,       82
Diphosphadithiatetrazocines      261
Diradical      223 224
Diselenadiazolyl radicals      217
Diselenium dinitride,       83
Disproportionation energies      218 226
Disulfur dinitride,       83 84
Ditelluradiazolyls, $[RCTe_2N_2]^{\bullet}$       31
Dithiadiazenes, ArNSNSAr'      284
Dithianitronium cation,       92
Dithiatetrazocines      64 72 248—250
Dithiatriazines      66 221 243
Dithiatriazyl cation,       95
Doping, halogens      281
Eight-membered rings,       36
Electrochemical reduction,       41 74
Electrochemical reduction,       43
Electrochemical studies      41 42 218—220
Electron density studies      187 197
Electron diffraction      31 32 144 145 187 245
Electron-counting procedure      5
Electron-rich aromatics      53 58
Electronegativities      1 166
Electronic structures      53—68
EPR spectroscopy      37—41 222

Ferromagnet      217
Fluxional process      37 75 254
Fremy's salt      37
Frontier orbital theory      69—73
Glass transition temperature ()      286 288
Glutathione peroxidase      302
Gunpowder reaction      164
Halogen exchange      133 150 152
Heat of formation,       85
Heterocyclothiazenes      259—273
Heterocyclothiazenes, bonding      60
Hueckel rule      5 53 58 91
Hund's rule      60
Hypervalent      299
Imidoselenium(II) dihalides      118—157
Imidoselenium(IV) dihalides      156
Imidosulfur(IV) dihalides      156
Imidotellurium dihalides      156
Imidotelluroxane      169
Infrared spectroscopy      46
Intermolecular $S{\dotsm}S$ interactions      62
Intermolecular $Te{\dotsm}N$ contacts      31
Intermolecular ${\pi}^*-{\pi}^*$ interactions      7 8
Intermolecular association      66—68
Intramolecular $Se{\dotsm}N$ interaction      299 302
Intramolecular ${\pi}^*-{\pi}^*$ interactions      6 7 65
Intramolecular chalcogen-chalcogen interactions      63—65
Intramolecular chalcogen-nitrogen interactions      294—306
Ionization potential, NS      81
Ionization potentials,       43
Ipsocentric ring current      59
Isolobal      60 73 240 260
Isotactic      290
Isotopic labelling, $^{33}S$       38
Isotopic substitution, $^{15}N$ , $^{34}S$ , $^{76}Se$ and $^{80}Se$       46 82
Jahn — Teller distortion      6 63 64 153 244 249—251
Macrocycles      287
Magnetic behaviour      7 68 219
Mass spectrometry      47
Matrix isolation      81 141
MCD spectroscopy      45
Metallic behaviour      218
Methane disulfonic acid, imido analogue      199
Methylenetriimido sulfate, $[CH_2S(N^tBu)_3]^{2-}$       198
Microwave spectroscopy      32 141 144 146 168
Molecular conductors      68 217 226
Molecular wires      57 285
N,N'-Dimethylthionitrosamine,       181
N,N'-Ureatotellurium imide      194
N-Halosulfinylamines      168
N-Thiosulfinylamines, RNSS      183
N-Thiosulfinylanilines      184
Negative hyperconjugation      48
Nitric oxide, biological storage      5
Nitric oxide, biological transport      171
Nitrogen diselenide,       82
Nitrogen disulfide,       82
NMR spectroscopy, $^{125}Te$       35
NMR spectroscopy, $^{14}N$       33
NMR spectroscopy, $^{15}N$       33—35 74 101 168 174 261
NMR spectroscopy, $^{33}S$       35
NMR spectroscopy, $^{77}Se$       35 36 305
NMR, inverse detection      35
Norbornadiene adduct,       69 243
Norbornadiene adduct,       261
Norbornadiene adduct,       84
Norbornadiene adduct,       95
Organoselenenyl azides,       201
Organoselenium(IV) azides      202
Organosulfenyl azides,       201
Organotellurium(IV) azides      202
Organotin derivative,       265
Oxidation states      2 8—10 296
Oxygen sensors      289
p-type doping      218 280
Paramagnetic ligand      220
Peierls instability      217
Pentaazidotellurite anion,       90
Pentafluorosulfur amine,       145
Pentasulfur hexanitride,       89
Perthionitrite anion,       164
Phosphazene-sulfanuric rings,       270
Phosphazene-thiazyl rings,       268
Photoelectron spectroscopy      43
Photoisomerization      251
Poly(sulfur nitride),       23 278—280
Poly(sulfur nitride), , bonding      56 57 279
Poly(thionylphosphazenes)      286—289
Poly(thiophosphazene)      285
Polymer, $(SNBr_{0.4})_x      262
Polymers,       212 281
Radical dimerization      66—68
Raman spectroscopy      46
Reactivity patterns      47—48
Regiochemistry      69
Rietveld analysis,       86
Ring contraction      74 87 153 174
Ring expansion      221 268
Ring-opening polymerization      269 285—287
S-Nitrososelenols, RSeNO      172
S-Nitrosothiols, RSNO      172
Sandwich complex, $(S_4N_4H_4)_2{\cdot}AgClO_4$       115
Selenazyl halides, complexes      144
Selenazyl monomer, SeN      81
Seleninylamine      169
Selenium(IV) diimides, RNSeNR      185 187 193
Selenodiselenazyl dichloride,       149
Selenonitrosoarenes      182
Selenonitrosyl, metal complex      81 124
Selenonium azides,       202
Silicon-nitrogen reagents      25
Spirocyclic sulfur(VI) system      269
Sulfanuric chloride,       24 153
Sulfanuric fluoride,       153
Sulfanuric polymers      269
Sulfanuric-phosphazene polymers      see “Polythionylphosphazenes”
Sulfenamido anion,       203
Sulfenyl nitrenes, RSN      201
Sulfimide anion, , complexes      209
Sulfinimidamide      191
Sulfinimidinates      170 191
Sulfonyl diimide,       197
Sulfonyl imide,       197
Sulfur diamides      see “Diaminosulfanes”
Sulfur diimide anions,       99 186
Sulfur diimide anions, , complexes      135
Sulfur diimide, HNSNH      99
Sulfur diimides, radical anions      190
Sulfur diimides, RNSNH      187
Sulfur diimides, RNSNR      186—193 281
Sulfur diimides, RNSNR, complexes      188
Sulfur diimides, unsymmetrical, ArNSNSAr'      284
Sulfur imide, SNH, complexes      131
Sulfur in liquid ammonia      34 101
Sulfur triimides,       146 197
Sulfur-nitrogen anions      34 98—103
Sulfur-nitrogen bonds, bent      113
Sulfur-nitrogen bonds, dissociation energies      172
Sulfur-nitrogen bonds, rotation barrier      172
Sulfur-nitrogen chains      56 57 281—285
Sulfur-nitrogen compounds, bonding      32
Sulfur-nitrogen radicals      37
Superconductor,       56 280
Syndiotactic      290
Tellurenamides      200
Tellurinylamines      see “Imidotelluroxanes”
Tellurium azides      90
Tellurium nitride      89
Tellurium(II) diamide      see “Diaminotellanes”
Tellurium(II) diamide, radical cation      201

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