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| de Boer J.H. — The dynamical character of adsorption |
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| Ïðåäìåòíûé óêàçàòåëü |
Absorption 48 230
Accommodation coefficient 24—28 33—34
Activation energy 96—98 225—6 231
Active spots 58—59 70—72
Adam, N. K. 103 104 106 111 123 129 141 171
Adsorbent, swelling of 230—2
Adsorption, activated 233
Allmand, A. J. 193 194
Alty, T. 52
Anisotropic molecules 150—4
applications of 2—3 9—10
Applications of entropy 53 99—101 112—20 161 163—4 234
Applications of heat of (see heat of adsorption), isobar 47—48
Applications of isostere 48
Applications of isotherm 45—47 (see Further under isotherm)
Applications of isotherm, kinetic theory of 1—3 40—47 54—56 61—65 91 94—99 102—3 117
Applications of isotherm, localized 56 120 213
Applications of isotherm, multi-molecular 41 61—85 89 200—19
Applications of isotherm, negative 100 103
Applications of mixtures 85—87
Applications of orces 31—32 185 200—1
Applications of rom solutions 46—47 87— 89 100 201
Applications on heterogeneous surfaces 70 190 209
Applications, rate of 11—12 225
Applications, restricted 75 82— 84
Applications, stepwise 191—5 203 207 209
Applications, super mobile 118 121
Applications, time of 3 29—31 34—36 40—45 63 90 194 200 234
Applications, unimolecular 45 47 54—56 60— 61 201
Area, critical 142 187
Area, molar 110—12
Area, surface 65 66 84 85 144 175 8 219
Armbruster, M. H. 144
Astronomical gas 10
Austin, J. B. 144
Bangham, D. H. 230
Barrer, R. M. 70 102 214 226 231
Basford, P. R. 144 167
Becker, J. A. 93
Bee, gas of super bees 13 38 43 93 97—98 229
Bemmelen, J. M. van 224 232
Benton, A. F. 193 194
Boer, J. H. do 24 32 53 59 70 94 115 116 119 120 146 151 152 168 197 210 218 219 230
Brunauer, S. 49 61 65 66 68 71 84 85 171 196 213 214 217 218 219 234
Burrage, L. J. 193
Calorimetric heat of adsorption 49
Capillaries, gas flow through 19 29—30 36—39 225—30
Capillaries, influence on multi-molecular adsorption 210—12
Cassel, H. 83 108 171 224
Catalysis 234
Chambers, H. H. 193 194
Chaplin, R. 193
Chemisorption 32 48 60 233 234
Cla,usius — Clapeyron equation 51 163 165
Clausing, P. 29 30 31 34 226
Cleaved surfaces 22
comet 11
Comparison with the heat of evaporation 52—53 66 72—74 100 216 17
Comparison, definitions 48 49
Comparison, differential 49 116
Condensation in adsorbed phase 130 134—41 157—68 180—90 198 201
Condensation, capillary 210—12
Coolidge, A. S. 102
Creeping of crystals 92
Critical area 142 187
Critical area, phenomena, two-dimensional 141—8 186—90 197—9
Critical area, pressure 142
Critical area, temperature, two-dimensional 142 145—7 153—6 168 187 195 198
Crystal growth 219—31
Custers, J. F. H. 152 210
Debye effect 133
Density measurement 41
Devonshire, A. F. 147
Diameter, Molecular 148 150 153 172—4
Diffraction of molecular waves 23
Diffusion 11 29—30 36—39 98 225—31
Diffusion, constant 225 227
Dipole forces 133—4 155—7
Dipoles, induced 148 150 153 168—9
Dipoles, influence on the two-dimensional critical temperature 155 168
Dippel, C. J. 230
Distillation, molecular (unobstructed path) 17
Dry atmospheres 7
Emanating from adsorbed layer underneath 200—2
Emmett, P. H. 61 65 66 68 71 84 85 213 214 217 219 234
Energy, activation 96—98 225—6 231
Entropy of adsorption 53 99—101 112— 20 140 161 163—4
Equations of state, two-dimensional 109— 10 124 128—32
Equilibrium, dynamic 14 44 50 56 62 98—99
Estermann, L. 23 220
Evaporation, latent heat of 50 66 216
Evaporation, rate of 13—18 51—52
Exchange of energy 26 90 95
Experimental values 34 41 70—74 102 114 116 194
Experimental values in capillaries 212
Fakhoury, N. 230
Force-area curves 138 144—5 159 62 164—7
Force-area curves, versus force curves 128—32 134—7 142
Fraser, R. G. J. 20
Frederikae, H. P. R. 41
Free path 4 9—10 13—14 94 227—30
Freeze drying 17 234
Frenkel, J. 30
Frequency, vibration 34 117—19 121—2
Freundlich, H. 123
Gas in astronomy 10
Gas of super bees 13 38 43 93 97— 98 229
Gas, kinetic picture 1 4
Gas, two-dimensional 1 4
Gave, R. 78
getters 10
Giauque, W. F. 41
Gibbs adsorption equation 106—7 117 123 125 143 170 178
Gregg, S. J. 219
Harkins, W. D. 144 145 167 189
Heat of adsorption and chemisorption 32
Heat of adsorption and physical adsorption 32—33
Heat of adsorption, assumption of constant value in Langmuir isotherm 58
Heller, G. 152
High vacua 9
Hiickel, E. 49 171
Hill, Terrell, H. 85 172 174 213 214 218
Holst, G. 29
Hopping molecule 95—98 120 175 226— 30
Houben, G. M. M. 89
Hysteresis 224 231—3
Influence on time of adsorption 30—31 35—36
Interaction between adsorbed molecules 72 133—4 155—7 185 213
Isosteric 49 117
Isotherm (adsorption) B.E.T. 65—66 75
Isotherm for a heterogeneous surface 195—7 208—10
Isotherm for a two-dimensional van der Waals equation 170—1 178—86 213
| Isotherm or multimolecular adsorption 202—7 210—14
Isotherm or restricted adsorption 83
Isotherm, B.E.T. generalized 61 65
Isotherm, experimental 72—74 77—79 84 102 232
Isotherm, Langinuir 54—61 67—68 79—81 174—8
Isotherm, Langmuir type 57—61 67—69 76 79—81 123—7 183 185—6 196
Isotherm, linear 45—47 110
Isotherm, reduced form 178 85
Isothermal 49
Isothermal of evaporation 50—51 53 216
Isothermal of spreading 101
Isothermal on heterogeneous surfaces 70
Isothermal, orientation of adsorbed molecules and 157—8
Isothermal, positive 99
Isothermal, variation with amount adsorbed 190 197
Isotopes, separation 16
Johnson, M. C. 31
Johnson, Th. H. 23
Jumps in adsorption isotherm 180—4 186 191—4 203 207 209
Jura, G. 144 145 167
Keesom effect 133 156
Kemball, C. 12 83 84 111 112 115 118 119 120 121 167 205 206
King, A. 193 194
Knauer, F. 22
Knudsen diffusion 29 227
Knudsen law 24 29
Knudsen, M. 4 25 27 28
Kramers, H. 234
Kruyer, S. 115 116 119 120 168 227 234
Langmuir (type) isotherm 54 61 67—69 76 79—81 123—7 149 171 174—8 183 185—6 196 214
Langmuir, I. 54 104 112
Lennard — Jones, J. E. 147
Lindemann, F. A. 34
Livingston, H. K. 174
Loeser, E. H. 144 167
London attraction 133 146
Mackay, C. A. 52
Maggs, F. A. P. 219
Magnified picture of adsorption (see Bee)
Magnus, A. 133 171
Manometer for low pressures 27—28
McBain, J. W. 230
Measurement of density 41
Measurement of low pressures 28
Measurement of the time of adsorption 29—30
Measurement of vapour pressure 15
Mignolet, J. C. P. 168
Migration, surface 56 90—99 219—21 220 226—30
Mohamed, A. F. 230
Molecular distillation 17
Molecular distillation, rays 20—24 33
Molecular distillation, velocity 4 6 22 226
Multimolecular adsorption 41 61—85 89 200—19
Neugebauer, N. 108
Nuclei 221—3
Number of molecules in a given volume 8 12 14
Number of molecules, striking a surface 4 14 18
Orientation of adsorbed molecules 134 140—1 150—61 168—9 195 200 205—8 224
Orr, W. J. C. 72 73 74
Oxide cathode 9
Phases, Condensed 140—1
Pockels, A. 104
Polarizability 134 151 153
Polarization 134 168—9 218—19
Pressure, two-dimensional (see Two-dimensional pressure)
Rate of adsorption 11—12 225
Rate of diffusion 225—30
Rate of evaporation 15—17 51—52
Rays, molecular 20—24 33
Razouk, R. I. 230
Reflection coefficient 24 45 52 234
Reflection coefficient on surfaces 20—24 33 41—42 51
Rideal, E. K. 83 93 103 104 111 112 123 129 130 131 141 171 226
Roberts, J. K. 25
Robins, A. B. 214
Rotation of adsorbed molecules 120 133 140 150—1
Saturation pressure, two-dimensional 38—39 162—8
Schofield, R. K. 131
Semenoff, N. 222
Separation of isotopes 16
Shereshefsky, J. L. 190 222
Sites of adsorption 55—56 65 99
Solutions, adsorption from 46—47 87—89 201
Spreading 90—93 101 104
Spreading, force 138—9
Standard state of adsorbed phase 111—12 115—16
Stem, O. 22 23
Stemerding, S. 234
Stout, J. W. 41
Supersaturation, two-dimensional 222 24 232
Surface, area 65—66 84—85 124 125 144 175—8 219
Surface, energy 105
Surface, migration 56 90—99 176 219—21 226—30
Surface, tension 104—8
Surfaces, heterogeneous 190—4
Surfaces, variations on 21 22 95 98
Swelling 230—2 234
Szyszkowski, B. von 123
Taylor, H. S. 233
Taylor, J. B. 24
Teller, E. 61 65 66 68 71 84 85 213 214 217 219 234
Temperature, two-dimensional critical 142 145—7 153—6 168 187 195 198
Thermal flow 18—19
Time of adsorption 3 29—31 34—36 40—45 63 90 200 226
Time of oscillation 30—31 33—34 44—45 96—97 121—2
Transitions between adsorbed phases 140—1 144—5
Traube, I. 107
Two-dimensional 124 133—4 139—40 146—50 154—8 165—6 168—9 172—4 176—7
Two-dimensional condensation (see Condensation in adsorbed phase)
Two-dimensional condensation from the adsorption isotherm 143
Two-dimensional condensation, expansion of adsorbents and 230
Two-dimensional condensation, Langmuir isotherm and 123
Two-dimensional condensation, measurement 104
Two-dimensional condensation, pressure critical 142
Two-dimensional condensation, saturation pressure 138—9 162 8
Two-dimensional condensation, standard 111 12
Two-dimensional condensation, surface tension and 104—6 143
Vacuum operations 9 17 234
Van der Waals constants a and b 146—8 150—1 173
Van der Waals forces 32—34 53 60 133 134 170 202 231 234
Vapour pressure 8 11—12 14—15 50—51
Velocity, mean molecular 4—6 22 226
Versus gas pressure 107—9
Vibrations of adsorbedmoleeules 34 117—19 121—2
Vick, F. A. 31
Volmer, M. 52 93 124 126 220
Volmer’s equation of state 124 126 176—8
Water proofing 92
Weir, C. E. 190 222
Wetting 90—93
White, T. A. 193 194
Woodhead, M. 102
Zwikker, C. 218
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