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de Boer J.H. Ч The dynamical character of adsorption
de Boer J.H. Ч The dynamical character of adsorption

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Ќазвание: The dynamical character of adsorption

јвтор: de Boer J.H.

јннотаци€:

Adsorption is the adhesion of atoms, ions, or molecules from a gas, liquid, or dissolved solid to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid (the absorbate) permeates or is dissolved by a liquid or solid (the absorbent). Note that adsorption is a surface-based process while absorption involves the whole volume of the material. The term sorption encompasses both processes, while desorption is the reverse of adsorption. It is a surface phenomenon.


язык: en

–убрика: ‘изика/

—татус предметного указател€: √отов указатель с номерами страниц

ed2k: ed2k stats

√од издани€: 1953

 оличество страниц: 252

ƒобавлена в каталог: 27.03.2013

ќперации: ѕоложить на полку | —копировать ссылку дл€ форума | —копировать ID
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ѕредметный указатель
Absorption      48 230
Accommodation coefficient      24Ч28 33Ч34
Activation energy      96Ч98 225Ч6 231
Active spots      58Ч59 70Ч72
Adam, N. K.      103 104 106 111 123 129 141 171
Adsorbent, swelling of      230Ч2
Adsorption, activated      233
Allmand, A. J.      193 194
Alty, T.      52
Anisotropic molecules      150Ч4
applications of      2Ч3 9Ч10
Applications of entropy      53 99Ч101 112Ч20 161 163Ч4 234
Applications of heat of (see heat of adsorption), isobar      47Ч48
Applications of isostere      48
Applications of isotherm      45Ч47 (see Further under isotherm)
Applications of isotherm, kinetic theory of      1Ч3 40Ч47 54Ч56 61Ч65 91 94Ч99 102Ч3 117
Applications of isotherm, localized      56 120 213
Applications of isotherm, multi-molecular      41 61Ч85 89 200Ч19
Applications of isotherm, negative      100 103
Applications of mixtures      85Ч87
Applications of orces      31Ч32 185 200Ч1
Applications of rom solutions      46Ч47 87Ч 89 100 201
Applications on heterogeneous surfaces      70 190 209
Applications, rate of      11Ч12 225
Applications, restricted      75 82Ч 84
Applications, stepwise      191Ч5 203 207 209
Applications, super mobile      118 121
Applications, time of      3 29Ч31 34Ч36 40Ч45 63 90 194 200 234
Applications, unimolecular      45 47 54Ч56 60Ч 61 201
Area, critical      142 187
Area, molar      110Ч12
Area, surface      65 66 84 85 144 175 8 219
Armbruster, M. H.      144
Astronomical gas      10
Austin, J. B.      144
Bangham, D. H.      230
Barrer, R. M.      70 102 214 226 231
Basford, P. R.      144 167
Becker, J. A.      93
Bee, gas of super bees      13 38 43 93 97Ч98 229
Bemmelen, J. M. van      224 232
Benton, A. F.      193 194
Boer, J. H. do      24 32 53 59 70 94 115 116 119 120 146 151 152 168 197 210 218 219 230
Brunauer, S.      49 61 65 66 68 71 84 85 171 196 213 214 217 218 219 234
Burrage, L. J.      193
Calorimetric heat of adsorption      49
Capillaries, gas flow through      19 29Ч30 36Ч39 225Ч30
Capillaries, influence on multi-molecular adsorption      210Ч12
Cassel, H.      83 108 171 224
Catalysis      234
Chambers, H. H.      193 194
Chaplin, R.      193
Chemisorption      32 48 60 233 234
Cla,usius Ч Clapeyron equation      51 163 165
Clausing, P.      29 30 31 34 226
Cleaved surfaces      22
comet      11
Comparison with the heat of evaporation      52Ч53 66 72Ч74 100 216 17
Comparison, definitions      48 49
Comparison, differential      49 116
Condensation in adsorbed phase      130 134Ч41 157Ч68 180Ч90 198 201
Condensation, capillary      210Ч12
Coolidge, A. S.      102
Creeping of crystals      92
Critical area      142 187
Critical area, phenomena, two-dimensional      141Ч8 186Ч90 197Ч9
Critical area, pressure      142
Critical area, temperature, two-dimensional      142 145Ч7 153Ч6 168 187 195 198
Crystal growth      219Ч31
Custers, J. F. H.      152 210
Debye effect      133
Density measurement      41
Devonshire, A. F.      147
Diameter, Molecular      148 150 153 172Ч4
Diffraction of molecular waves      23
Diffusion      11 29Ч30 36Ч39 98 225Ч31
Diffusion, constant      225 227
Dipole forces      133Ч4 155Ч7
Dipoles, induced      148 150 153 168Ч9
Dipoles, influence on the two-dimensional critical temperature      155 168
Dippel, C. J.      230
Distillation, molecular (unobstructed path)      17
Dry atmospheres      7
Emanating from adsorbed layer underneath      200Ч2
Emmett, P. H.      61 65 66 68 71 84 85 213 214 217 219 234
Energy, activation      96Ч98 225Ч6 231
Entropy of adsorption      53 99Ч101 112Ч 20 140 161 163Ч4
Equations of state, two-dimensional      109Ч 10 124 128Ч32
Equilibrium, dynamic      14 44 50 56 62 98Ч99
Estermann, L.      23 220
Evaporation, latent heat of      50 66 216
Evaporation, rate of      13Ч18 51Ч52
Exchange of energy      26 90 95
Experimental values      34 41 70Ч74 102 114 116 194
Experimental values in capillaries      212
Fakhoury, N.      230
Force-area curves      138 144Ч5 159 62 164Ч7
Force-area curves, versus force curves      128Ч32 134Ч7 142
Fraser, R. G. J.      20
Frederikae, H. P. R.      41
Free path      4 9Ч10 13Ч14 94 227Ч30
Freeze drying      17 234
Frenkel, J.      30
Frequency, vibration      34 117Ч19 121Ч2
Freundlich, H.      123
Gas in astronomy      10
Gas of super bees      13 38 43 93 97Ч 98 229
Gas, kinetic picture      1 4
Gas, two-dimensional      1 4
Gave, R.      78
getters      10
Giauque, W. F.      41
Gibbs adsorption equation      106Ч7 117 123 125 143 170 178
Gregg, S. J.      219
Harkins, W. D.      144 145 167 189
Heat of adsorption and chemisorption      32
Heat of adsorption and physical adsorption      32Ч33
Heat of adsorption, assumption of constant value in Langmuir isotherm      58
Heller, G.      152
High vacua      9
Hiickel, E.      49 171
Hill, Terrell, H.      85 172 174 213 214 218
Holst, G.      29
Hopping molecule      95Ч98 120 175 226Ч 30
Houben, G. M. M.      89
Hysteresis      224 231Ч3
Influence on time of adsorption      30Ч31 35Ч36
Interaction between adsorbed molecules      72 133Ч4 155Ч7 185 213
Isosteric      49 117
Isotherm (adsorption) B.E.T.      65Ч66 75
Isotherm for a heterogeneous surface      195Ч7 208Ч10
Isotherm for a two-dimensional van der Waals equation      170Ч1 178Ч86 213
Isotherm or multimolecular adsorption      202Ч7 210Ч14
Isotherm or restricted adsorption      83
Isotherm, B.E.T. generalized      61 65
Isotherm, experimental      72Ч74 77Ч79 84 102 232
Isotherm, Langinuir      54Ч61 67Ч68 79Ч81 174Ч8
Isotherm, Langmuir type      57Ч61 67Ч69 76 79Ч81 123Ч7 183 185Ч6 196
Isotherm, linear      45Ч47 110
Isotherm, reduced form      178 85
Isothermal      49
Isothermal of evaporation      50Ч51 53 216
Isothermal of spreading      101
Isothermal on heterogeneous surfaces      70
Isothermal, orientation of adsorbed molecules and      157Ч8
Isothermal, positive      99
Isothermal, variation with amount adsorbed      190 197
Isotopes, separation      16
Johnson, M. C.      31
Johnson, Th. H.      23
Jumps in adsorption isotherm      180Ч4 186 191Ч4 203 207 209
Jura, G.      144 145 167
Keesom effect      133 156
Kemball, C.      12 83 84 111 112 115 118 119 120 121 167 205 206
King, A.      193 194
Knauer, F.      22
Knudsen diffusion      29 227
Knudsen law      24 29
Knudsen, M.      4 25 27 28
Kramers, H.      234
Kruyer, S.      115 116 119 120 168 227 234
Langmuir (type) isotherm      54 61 67Ч69 76 79Ч81 123Ч7 149 171 174Ч8 183 185Ч6 196 214
Langmuir, I.      54 104 112
Lennard Ч Jones, J. E.      147
Lindemann, F. A.      34
Livingston, H. K.      174
Loeser, E. H.      144 167
London attraction      133 146
Mackay, C. A.      52
Maggs, F. A. P.      219
Magnified picture of adsorption      (see Bee)
Magnus, A.      133 171
Manometer for low pressures      27Ч28
McBain, J. W.      230
Measurement of density      41
Measurement of low pressures      28
Measurement of the time of adsorption      29Ч30
Measurement of vapour pressure      15
Mignolet, J. C. P.      168
Migration, surface      56 90Ч99 219Ч21 220 226Ч30
Mohamed, A. F.      230
Molecular distillation      17
Molecular distillation, rays      20Ч24 33
Molecular distillation, velocity      4 6 22 226
Multimolecular adsorption      41 61Ч85 89 200Ч19
Neugebauer, N.      108
Nuclei      221Ч3
Number of molecules in a given volume      8 12 14
Number of molecules, striking a surface      4 14 18
Orientation of adsorbed molecules      134 140Ч1 150Ч61 168Ч9 195 200 205Ч8 224
Orr, W. J. C.      72 73 74
Oxide cathode      9
Phases, Condensed      140Ч1
Pockels, A.      104
Polarizability      134 151 153
Polarization      134 168Ч9 218Ч19
Pressure, two-dimensional      (see Two-dimensional pressure)
Rate of adsorption      11Ч12 225
Rate of diffusion      225Ч30
Rate of evaporation      15Ч17 51Ч52
Rays, molecular      20Ч24 33
Razouk, R. I.      230
Reflection coefficient      24 45 52 234
Reflection coefficient on surfaces      20Ч24 33 41Ч42 51
Rideal, E. K.      83 93 103 104 111 112 123 129 130 131 141 171 226
Roberts, J. K.      25
Robins, A. B.      214
Rotation of adsorbed molecules      120 133 140 150Ч1
Saturation pressure, two-dimensional      38Ч39 162Ч8
Schofield, R. K.      131
Semenoff, N.      222
Separation of isotopes      16
Shereshefsky, J. L.      190 222
Sites of adsorption      55Ч56 65 99
Solutions, adsorption from      46Ч47 87Ч89 201
Spreading      90Ч93 101 104
Spreading, force      138Ч9
Standard state of adsorbed phase      111Ч12 115Ч16
Stem, O.      22 23
Stemerding, S.      234
Stout, J. W.      41
Supersaturation, two-dimensional      222 24 232
Surface, area      65Ч66 84Ч85 124 125 144 175Ч8 219
Surface, energy      105
Surface, migration      56 90Ч99 176 219Ч21 226Ч30
Surface, tension      104Ч8
Surfaces, heterogeneous      190Ч4
Surfaces, variations on      21 22 95 98
Swelling      230Ч2 234
Szyszkowski, B. von      123
Taylor, H. S.      233
Taylor, J. B.      24
Teller, E.      61 65 66 68 71 84 85 213 214 217 219 234
Temperature, two-dimensional critical      142 145Ч7 153Ч6 168 187 195 198
Thermal flow      18Ч19
Time of adsorption      3 29Ч31 34Ч36 40Ч45 63 90 200 226
Time of oscillation      30Ч31 33Ч34 44Ч45 96Ч97 121Ч2
Transitions between adsorbed phases      140Ч1 144Ч5
Traube, I.      107
Two-dimensional      124 133Ч4 139Ч40 146Ч50 154Ч8 165Ч6 168Ч9 172Ч4 176Ч7
Two-dimensional condensation      (see Condensation in adsorbed phase)
Two-dimensional condensation from the adsorption isotherm      143
Two-dimensional condensation, expansion of adsorbents and      230
Two-dimensional condensation, Langmuir isotherm and      123
Two-dimensional condensation, measurement      104
Two-dimensional condensation, pressure critical      142
Two-dimensional condensation, saturation pressure      138Ч9 162 8
Two-dimensional condensation, standard      111 12
Two-dimensional condensation, surface tension and      104Ч6 143
Vacuum operations      9 17 234
Van der Waals constants a and b      146Ч8 150Ч1 173
Van der Waals forces      32Ч34 53 60 133 134 170 202 231 234
Vapour pressure      8 11Ч12 14Ч15 50Ч51
Velocity, mean molecular      4Ч6 22 226
Versus gas pressure      107Ч9
Vibrations of adsorbedmoleeules      34 117Ч19 121Ч2
Vick, F. A.      31
Volmer, M.      52 93 124 126 220
VolmerТs equation of state      124 126 176Ч8
Water proofing      92
Weir, C. E.      190 222
Wetting      90Ч93
White, T. A.      193 194
Woodhead, M.      102
Zwikker, C.      218
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